Reactivity 1.3 Energy from Fuels
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Standard enthalpy of combustion
The enthalpy evolved when one mole of the substance in its standard state combusts completely in oxygen under standard.
Formula for specific energy of a fuel
enthalpy of combustion/molar mass
What are fossil fuels formed from?
Buried organisms that have undergone reduction under pressure
Three main fossil fuels
Coal, crude oil, natural gas
What are oil and natural gas formed from?
The anaerobic decomposition of marine organisms
What is coal formed from?
Terrestrial vegetation
Crude oil
A complex mix of straight chain, branched, cyclic and aromatic hydrocarbons, although it mainly consists of alkanes.
Advantages of Natural Gas
Clean, easily transported, higher specific energy than coal or oil
Advantages of oil
Easily transported by pipelines/tankers, feedstock for organic chemicals, convenient fuel for vehicles
Advantages of coal
Present in large quantities, widely distributed, can be converted into synthetic liquids and gases, feedstock for organic chemicals, releases more energy than renewable sources, safer than nuclear energy, longer lifespan than natural gas or oil
Disadvantages of Natural Gas
Contributes to global warming, limited lifespan, uneven distribution
Disadvantages of oil
Contributes to global warming/acidic rain, limited lifespan, risk of marine pollution due to oil spills
Disadvantages of coal
Contributes to global warming/acidic rain, not as easily transported, dangerous to mine, cause pollution, dirty
The Greenhouse Effect
The process where certain gases in the Earth’s atmosphere trap heat and warm the planet. These gases absorb infrared radiation emitted by the Earth’s surface, preventing it from escaping into space, and re-radiate some of it back to the surface, thus warming the planet.
What do greenhouse gases allow to pass through vs re-radiate?
Shortwave radiation from the sun is able to be passed through. Absorb the longer wavelength IR radiation re-radiated from the earths surface.
What makes a vibrational mode of a carbon dioxide molecule IR active
If it results in a change of dipole
IR active vibrational modes of CO2
Asymmetric stretch, Two symmetric bends
IR inactive vibrational mode of CO2
Symmetric stretch
Carbon footprint
The total amount of greenhouse gases produced during human activities.