C.5 Chemical Changes
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Metal + Oxygen
Metal Oxide
What is reduction (e-)
• OILRIG • Reduction is gain of electrons • Fe2+ +2e- -> Fe
What is oxidation (e-)
OIL RIG • Oxidation is loss of electrons • ca -> ca2+ +2e-
What is oxidation
• When a substance is oxidised it gains oxygen • 2Mg + O2 -> 2MgO
What is reduction
• When a substance looses oxygen -Fe2O3+3CO -> 2Fe + 3CO2
Why do displacement reactions happen
A more reactive metal displaces a less reactive metal from a compound
What determines how reactive a metal is
• How easily it looses its outer shell electron
What happens when metals react with water
• Metal + Water -> Metal Hydroxide + Hydrogen • (Just split the water up) • 2K +2H2O -> 2KOH + H2 • The higher up the reactivity series the more vigorous the reaction
Metal + Acid
• Metal + Acid ->Salt + Hydrogen • Metals below hyrdogen do not react
Reactivity series
Potassium Sodium Calcium Magnesium Aluminium (Carbon) Zinc Iron Tin Lead (Hydrogen) Copper Silver Gold Platinum Please, stop lovingly calling me a cute zebra instead try learning how cows scran grass period.
Why gold, silver and platinum found as a metal and not a compound
• As they have low reactivity • Do not react with oxygen
What determines if a metal can be extracted by reduction carbon
• If they are below Carbon in the reactivity series • Process called smelting • Metal Oxide + Carbon -> Metal + Carbon dioxide
what is an ore
a material containing enough metal to make it economical to extract
How do you write half equations
• Write out the equation with ions • Cross out spectator ions (those that don’t change)
why are new methods of extracting copper needed
• As high grade copper ores are becoming depleted • New methods which can extract metal from low - grade copper ore
Bio leaching
• Bacteria is poured into the area • Bacteria can break down low grade ores • Produces an acidic solution called leachate • Either Electrolysis is used to obtain copper • Or displacement using scrap iron
Phytomining
• Cabbages are planted on low grade ore site • They take up copper in their roots • Once grown they are burned • Ash is dissolved in sulphuric acid to make solution containing copper compounds
Pro and Con of Bioleaching
Con - Very slow (can take years) - Some toxic chemicals may be released which harms wildlife Pro - Reduces need to obtain new ores by mining - Conserves limited supply of high grade ore
Pro and Con : Phytomining
Con - Slow process Pro - Reduces need to obtain new ores by mining - Conserves limited supply of high grade ore
What is corrosion
• Destruction of metal when it reacts with the atmosphere
What is rusting
• Rusting is the destruction of iron • In the presence of water and oxygen
How can corrosion be prevented
• Own protective layer • Grease +oil • Paint • Electroplating (covering with a less reactive metal) • Sacrificial metal (covering with more reactive metal)
Why does aluminium not corrode like other metals
• Oxygen reacts with the top layer of aluminium • produces aluminium oxide • doesn’t flake away
Sacrificial protection
• Place a block of more reactive metal on top (doesn’t have to fully cover the metal) • It will react first • The metal you are protecting is galvanised • for iron zinc is used • on ships mg is used