Definitions
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What are isotopes?
• Atoms of the same element which therefore have the same number of protons and electrons but a different number of neutrons
What is relative isotopic mass?
• The mass of an isotope relative to 1/12th of the mass of an atom of carbon-12
What is relative atomic mass?
• The weighted mean mass of an atom of an element relative to 1/12th of the mass of an atom of carbon-12
What is ionic bonding?
• The electrostatic attraction between positive and negative ions
What is an ionic lattice?
• A repeating pattern of oppositely charged ions
What is covalent bonding?
• The strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms
What is electronegativity?
• The ability of a bonded atom to attract the bonding electrons in a covalent bond
What is a hydrogen bond?
• A special type of permanent dipole-dipole interaction found between molecules containing: • an electronegative atom (such as F, O and N) with a lone pair of electrons • a hydrogen atom bonded to an electronegative atom
What is a homologous series?
• A series of organic compounds with the same functional group but with each successive member differing by CH2
What is an empirical formula?
• The simplest whole number ratio of atoms of each element present in a compound
What are structural isomers?
• Compounds with the same molecular formula but different structural formulae
What is homolytic fission?
• Each atom takes one of the electrons from the covalent bond, which causes the formation of 2 radicals
What is a radical?
• A species with an unpaired electron
What is heterolytic fission?
• When one of the atoms takes both electrons during the breaking of the covalent bond
What is a curly arrow?
• The movement of an electron pair, showing either: • the formation of a covalent bond • heterolytic fission
What are stereoisomers?
• Compounds with the same structural formula but with a different arrangement in space
What is E/Z isomerism?
• A type of stereoisomerism in which different groups attached to each carbon of a C=C double bond may be arranged differently in space because of the restricted rotation of the C=C bond
What is cis-trans isomerism?
• A type of E/Z isomerism where there are 2 non-hydrogen groups and 2 hydrogen atoms around the carbon-carbon double bond
What is an electrophile?
• An electron pair acceptor • (They’re usually a positive ion or a molecule containing an atom with a partial positive charge)
What is a nucleophile?
• An electron pair donor
What are optical isomers?
• Non-superimposable mirror images