Acids, bases and buffers
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Lewis acid
electron pair acceptor
Lewis base
electron pair donor
Bronsted Lowry base
proton acceptor
Bronsted-Lowry acid
proton donor
Dibasic acid
can form 2 conjugate bases
Conjugate acid base
HA + B -> HB+ + A- acid + base Conjugate acid + conjugate base
tribasic acid
can form 3 conjugate bases
Strong acid
completely dissociate in aqueous solutions to produce H+ ions large Ka smaller pKa
Weak acid
partially dissociate in aqueous solutions to produce H+ ions small Ka larger pKa
Acid dissociation constant
ka = [H+][A-] / [HA] = [H+]^2/[HA]
pH
-log10[H+] measure of hydrogen ion concentration in solution
[H+] from pH
10^-pH
[H+] from acid dissociation constant
√(ka x [HA])
pKa
-log10Ka
Ionic product of water formula
Kw = [OH-][H+] = 1 x 10^-14
Buffer solution
• solution that resists change in pH • when small quantity of acid or alkali is added
Ka of buffer solution
[salt] x [H+] / [HA]
Concentrations after dilution
(intital volume/total volume) x conc
End point
point where pH changes rapidly
Equivalence point
point where enough acid has been added to react completely with all the base
Larger Ka, smaller pKa
• stronger acid • dissociates more readily in solution • equilibrium lies more to the right
Limitations of Ka for stronger weak acids
• [HA] equilibirum ~ [HA] undissociated • [HA] is bigger than [H+] • Negligible dissociation of H2O
Buffer explanation
• weak acid and soluble salt of weak acid • H+ added, conjugate base reacts, equilibrium shift to the left 3.OH- added, H+ bond, equilibrium shifts to the right
Carbonic acid hydrogencarbonate
CO2(g) +H2O(l) ⇌ H2CO3(aq) ⇌ H+(aq) +HCO3-(aq) • maintains blood pH 7.4 • H+ shifts both equilibrium to the left • OH- shifts equilibrium to the right