states of matter
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What kinetic assumptions are made when dealing with an ideal gas?
• The gas contains a large number of molecules moving in random directions at random speeds. • Electrostatic forces between molecules is negligible, except during collisions. • Collisions are perfectly elastic. • Time of collisions between molecules is negligible compared to time between collisions. • The molecules of a gas occupy negligible volume compared to the total volume of the gas.
What kinetic assumptions are made when dealing with an ideal gas?
• The gas contains a large number of molecules moving in random directions at random speeds. • Electrostatic forces between molecules is negligible, except during collisions. • Collisions are perfectly elastic. • Time of collisions between molecules is negligible compared to time between collisions. • The molecules of a gas occupy negligible volume compared to the total volume of the gas.
What are the conditions necessary for a gas to approach ideal behaviour?
● Low pressure ● High temperature
What are the limitations of an ideal gas at very low temperatures and very high pressures?
● Intermolecular forces are no longer negligible and have to be considered. ● Molecular size is also no longer negligible and has to be considered.
What is the ideal gas equation?
pV = nRT p - pressure (Pa) V - volume (m3) n - number of moles (mol) R - gas constant (8.314 J K-1 mol-1) T - temperature (K)
The ideal gas equation can be used with which other equation to find molecular mass?
M = m/n M - molecular mass n - number of moles (mol) m - mass (g)
Use the kinetic-molecular model to describe the liquid state
● Particles are close together but not regularly arranged. ● Particles have a little more kinetic energy than in a solid. ● There are fewer electrostatic forces between particles than in a solid, allowing particles to move past each other and flow.
In terms of the kinetic-molecular model, what happens during melting?
● Solid → Liquid ● Increasing the temperature of the surroundings causes particles to absorb energy meaning they gain more kinetic energy. ● Eventually, the particles gain enough energy to disrupt the regular arrangement and become a liquid.
How do particles act during vaporisation?
● Liquid → Gas ● Heat energy causes particles in a liquid to move fast enough to break all forces of attraction between them and become a gas.
What is vapour pressure?
When a liquid evaporates in a closed container, the gaseous particles move around above the liquid. When these particles collide with the walls of the container, they exert a pressure called the vapour pressure.
Describe the structure of a solid ionic compound
● Regular, repeating arrangement (lattice). ● Caused by the electrostatic attraction between the oppositely charged ions.
Describe the lattice structure of iodine
● Iodine is an example of a simple molecular lattice. ● Iodine, I2 molecules form a larger structure due to intermolecular forces (Van der Waals Forces) between molecules. ● The structure is described as face centred cubic.
What is an allotrope?
Allotropes are different physical forms of an element in the same state.
Describe the structure of a fullerene
Lattice structure E.g. a buckminsterfullerene (C60) is a molecule consisting of 60 carbon atoms arranged in pentagons and hexagons.
What is a nanotube?
A graphene sheet rolled up into a tube (single sheet of carbon atoms covalently bonded together)
Describe the structure of diamond
● Giant covalent lattice. ● Each carbon atom is covalently bonded to four other carbon atoms. ● Extremely strong structure. ● Bond shape and angle around each carbon: Tetrahedral, 109.5°.
Describe the structure of graphite
● Giant covalent lattice. ● Made from layers of carbon arranged in hexagonal rings. ● There are weak london forces between layers. ● Each carbon atom bonds covalently to 3 other carbon atoms. ● One delocalised electron per carbon.
Describe the structure of graphene
● Giant covalent lattice. ● Single layer of graphite. ● Each carbon atom is bonded to 3 other carbon atoms to create a hexagonal ringed structure. ● One delocalised electron per carbon.
Describe the structure of silicon(IV) oxide
Describe the structure of silicon(IV) oxide ● Similar 3D structure to diamond. ● Silicon and oxygen atoms covalently bonded together.
Describe the structure of ice
Describe the structure of ice ● Open lattice structure. ● Hydrogen bonds hold water molecules apart in hexagonal rings.
Describe the structure of a metal (e.g. copper)
Giant metallic lattice with positive ions packed closely together with delocalised electrons. In copper, each atom is surrounded by 12 other copper atoms.
What does a diagram of metallic bonding look like?
● Positive charges = ions ● Negative charges = electrons
What is a finite resource?
A resource that is used up faster than it is replaced. This resource will run out if it is continually used.
Why is recycling important?
● To conserve finite resources for as long as possible by reducing the rate at which the are used. ● Reduces greenhouse gas emissions (which cause global warming). ● May reduce costs and other environmental impacts of a material.