5.2 Quantitative Analysis
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Titration
Allows you to find the exact volume of acid needed to neutralise an alkali or vice versa
Describe how to carry out a titration to calculate a substance’s concentration
1- Use a pipette to measure a set volume of acid/alkali of unknown concentration into a flask and add an indicator 2- Fill the burette with a known concentration of acid/alkali 3- Use the burette to slowly add the liquid with known concentration to the liquid with unknown concentration 4- When the indicator changes colour the unknown concentration substance has been neutralised. 5- Record the volume of known concentration liquid and repeat until you get concordant titres
Titre
The volume recorded in titration
How to do titration more accurately
-Swirl the flask regularly -Place the conical flask on a white tile -Read from meniscus -Add burette solution one drop at a time near end point -Make sure no air bubbles in burette -Wash inside of conical flask with deionised water -Wash burette with solution before titration
Why should the conical flask be placed on a white tile for titration
So that the colour change is easier to see
Where should volumes be read from
At eye level from the bottom of the meniscus
Molar volume
The volume occupied by one mole of gas
Formula for molar volume
Molar volume = gas volume / number of moles
Avagadro’s law
Under the same conditions the same number of moles of different gases will occupy the same volume
How much volume does 1 mole of gas take up at room temperature and pressure
24dm3
Atom economy
What percentage of the mass of the reactants has been converted into the desired product when manufacturing a chemical
Atom economy formula
Atom economy = (total Mr of desired products) / (total Mr of all products) x100
100% atom economy
All the atoms in the reactants have been turned into useful products
Disadvantages of low atom economy reactions
-Unsustainable -Not very profitable
Why are low atom economy reactions unsustainable
-They use up resources quickly -They make lots of waste resources that have to disposed of somehow
Why are low atom economy reactions unprofitable
Raw materials can be expensive to buy and waste products can be expensive to dispose of responsibly
How to increase the atom economy of a process
Find a use for the waste products rather than throwing them away
Factors to consider in industrial reactions
-Atom economy -Percentage yield -Rate of reaction -If the reaction’s reversible
Theoretical yield
The mass of product you’d make if all reactants were converted to products
Actual yield
The amount of product you get from a reaction
Percentage yield formula
Percentage yield = (actual yield) / (theoretical yield) x100
Why is the percentage yield never 100%
-Incomplete reactions -Practical losses -Unwanted reactions
Why might incomplete reactions mean that percentage yield is not 100%
If not all reactants are converted to product, the reaction is incomplete and the yield will be lower than expected
Why might practical losses mean that percentage yield is under 100%
You always lose a bit when you transfer chemicals between containers- some is left on the inside surface of the old container