Reactivity trends
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what happens to reactivity down group 2?
reactivity increases
what reactions do group 2 elements undergo? (and products)
redox with: - oxygen (metal oxide) - water (metal hydroxide + H2) - acid (salt + H2)
what happens to ionisation energy down group 2?
IE decreases
what observations would be made when group 2 reacts with water?
• increase in pH (shown by indicator) • solid precipitate once the solution becomes saturated (group 2 hydroxide are sparingly soluble)
what happens to solubility down group 2 hydroxides? and what effect does this have on pH?
solubility increases which increases [OH-] so increases pH
uses of group 2 compounds
• Ca(OH)2 used in agriculture (as lime) to increase pH of acidic soils (producing water) • Mg(OH)2 or CaCO3 used in antacids (treating acid indigestion) by neurtalising HCl/stomach acid
what happens to boiling point down group 7?
boiling point increases (more e-, stronger LDFs)
chlorine state and colour (RTP)
pale green gas
bromine state and colour (RTP)
red-brown liquid with orange vapour
iodine state and colour (RTP)
solid grey-black crystals
what reactions do halogens undergo?
• redox • halogen-halide displacement
what happens in halogen-halide displacement?
more reactive halogen displaces the halide from solution (causes colour change)
reaction and colour change when I-(aq) is mixed with Cl2(aq)
2I- + Cl2 –> I2 + 2Cl- pale green to violet
colours of Cl2, Br2, I2 in water
Cl2 - pale green Br2 - orange I2 - brown
colours of Cl2, Br2, I2 in cyclohexane
Cl2 - pale green Br2 - orange I2 - violet
how can you tell apart solutions of iodine and bromine in water?
• add cyclohexane and shake mixture • halogens will dissolve more readily • colours will be more obvious
fluorine state and colour
pale yellow gas
disproportionation
redox reaction in which the same element is both oxidised and reduced
two examples of disproportionation
• Cl2 + H2O • Cl2 + NaOH
how is Cl used in disinfectant and water sterilisation?
chlorate, ClO- ions kill bacteria
how can you demonstrate ClO- acting as bleach?
• mix Cl2 + H2O • add indicator • indicator will turn red (HCl and HClO are acidic) then colour will disappear as it is bleached
why would use dissolve NaOH in water before adding Cl2?
• Cl2 is sparingly soluble in water • more Cl2 dissolves in the presence of NaOH • Cl2 reacts with NaOH in a disproportionation reaction to form ClO-
risks of chlorine use
• Cl2 reacts with organic hydrocarbons such as methane from decaying vegetation • this forms chlorinated hydrocarbons which are suspected carcinogens
benefits of chlorine use
• prevent outbreaks of waterborne diseases like typhoid and cholera