Unit 2: Nature's Chemistry
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Homologous Series
Series of molecules with similar chemical properties and which share the same general formula
Alkanes
Names all end in -ane General Formula is CnH2n+2
Alkenes
Names all end in -ene All contain a carbon to carbon double bond (Unsaturated) Have the general formula CnH2n
Unsaturated Hydrocarbons
Decolourise bromine water quickly
Cycloalkanes
Begin with cyclo- and end with -ane Have the general formula CnH2n
Combustion Reactions
Hydrocarbon + Oxygen → Carbon Dioxide + Water
Addition Reactions
Double bond of alkene partially breaks, joining to the reactant molecule
Hydrogenation
Addition of hydrogen to an alkene, turning it into an alkane
Hydration
Addition of water to an alkene
Isomers
Compounds with the same molecular formulae but different structural formulae
Exothermic Reaction
Releases Heat Energy
Endothermic Reaction
Take in Heat Energy
Alkanols - Functional Group
Hydroxyl (OH)
Alkanols - General Formula
CnH2n+1OH
Alkanols - Naming
Ends in -anol Number of carbon with hydroxyl group attached is lowest (butan-1-ol)
Alkanols - Properties
Highly Flammable Boiling points increase with size of molecule as inter-molecular forces increase
Alkanols - Reactions
Combustion: Alkanol + Oxygen → Carbon Dioxide + Water Condensation with carboxylic acids to make esters
Alkanols - Uses
Alcoholic Drinks (Ethanol) Fuels (All Alcohols) - Methanol + Ethanol very clean burning Solvents Making Esters
Carboxylic Acids - Functional Group
Carboxyl -COOH

Carboxylic Acids - Naming
• oic acid eg. ethanoic acid (vinegar) • *Carbon within carboxylate always number 1*
Carboxylic Acids - General Formula
CnH2n+1COOH
Carboxylic Acids - Properties
Boiling point increases with size due to increasing intermolecular forces
Carboxylic Acids - Reactions
Same as all Acids Metal + Acid → Salt + Hydrogen Base + Acid → Water + Salt Carbonate + Acid → Salt + Carbon Dioxide + Water Ethanoic Acid → Ethanoate (CH3COO-) Condensation Reaction with alcohols to make esters
Carboxylic Acids - Uses
Cleaning Products (Limescale Remover) Preservative