Chemistry Module 2 Explanations
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Units in the Ideal Gas Equation?
Pressure = Pascals Volume = m^3 n = mol Temperature = Kelvin (C+273)
Explaining reactivity trends (metals)
• Reactivity increases down group • Atomic radii increase (there are more shells) • There is more shielding • Nuclear attraction decreases (increased shielding and distance outweigh increased nuclear charge) • Easier to remove outer electrons 6.Ionisation energy decreases
Explaining reactivity trends (halogens)
• Reactivity decreases down group • Atomic radii increase (there are more shells) • There is more shielding • Nuclear attraction decreases (increased shielding and distance outweigh increased nuclear charge) • Harder to attract outer electrons • Ionisation energy increases
Use for NaClO
Bleach
Number of orbitals in an s subshell
1
Number of orbitals in a p subshell
3
Number of orbitals in a d subshell
5
Number of orbitals in a f subshell
7
Explain why liquid water is denser than solid ice
In solid state H2O molecules are held apart by hydrogen bonds (it has an open lattice structure)
Explain why H2O has a relatively high boiling point / melting point
(Relatively strong) hydrogen bonds need to be broken. A lot of energy is needed to overcome these.
Explain the melting / boiling pt of a giant covalent structure
High melting boiling point Due to strong covalent bonds (sigma bonds) between atoms that require large amts of energy to overcome
Explain the melting / boiling pt of a giant ionic lattice
High melting/ boiling point Due to strong electrostatic attraction between ions
Explain the structure and bonding of a metal
• Metals have a giant structure • There is metallic bonding, with positive ions and delocalised electrons • There is electrostatic attraction between positive ions and electrons
Explain the melting / boiling pt of a small covalent molecule
• Though atoms within molecules bonded strongly, molecules are held together by weak intermolecular forces • Intermolecular forces/van der Waals forces don’t need a lot of energy to overcome Only the intermolecular forces are overcome during melting and boiling, not the covalent bonds
Explain the conductivity of a giant covalent structure
Poor conductivity regardless of state Due to no ions being presetn Can’t carry charge
Explain the conductivity of a giant ionic lattice
When solid, poor conductivity Due to ions being held in place by lattice structure, so ions aren’t free to move When molten or aqueous, high conductivity Due to ions being free to move
Explain the conductivity of a metallic structure
High conductivity due to structure Electrons are delocalised, so are free to carry charge
Explain the conductivity of a small covalent molecule
No mobile charged particles: simple molecules never conduct electricity
Explain London forces / Induced dipole-dipole interactions
• Electrons in an atom/molecule are constantly moving • A temporary uneven distribution of electrons occurs for an instant: an instantaneous dipole 3.The instantaneous dipole induces a dipole in its neighbours • Leads to attraction
Explain the trend of melting / boiling pts of non-polar molecules
1.Non-polar molecules only have London forces between molecules 2. As molecules get larger, the number of electrons increases 3. Size of the induced dipoles also get larger, giving stronger forces
State of an ideal gas
Particles are in random motion Collisions between particles are elastic Particles have negligible size There are no intermolecular forces
Theoretical yield is difficult to achieve as
Reaction may not have gone to completion Other reactions may have taken place simultaneously Purification may result in loss of product
Uses of titrations
Find the concentration of a solution Test the purity of a substance Identify an unknown chemical
Solubility of ionic compounds
Ionic compounds are soluble in polar solvents