Alcohols (P2+P3)
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Name the mechanism, reagents and conditions from alkene to alcohol.
Direct hydration reagents: steam conditions and catalyst: conc H3PO4
2 advantages of hydration of ethene
high rate of reaction high purity product made
2 disadvantages of hydration of ethene
high temp and pressure needed; increased cost crude oil is non renewable
2 advantages of fermentation
uses renewable resources low cost
2 disadvantages of fermentation
slow rate of reaction less efficient
What is biofuel?
a fuel produced from biomass (renewable plant material)
2 advantages of biofuel
carbon neutral comes from renewable raw materials
2 disadvantages of biofuel
food prices rise as crops used for biofuels the supply of biofuels is dependent on crop harvest so is less reliable.
Name of mechanism, reagents and conditions from alcohols to alkenes.
elimination (dehydration) reagent: H2SO4 conditions: hot, conc
Oxidation of primary alcohol under distillation forms an… under what reagent and conditions observation?
Aldehyde reagent: acidified potassium dichromate conditions: distillation observation: orange to green
Ehanol oxidised to ethanal equation
CH3CH2OH + [O] –> CH3CHO +H2O
Oxidation of primary alcohol under reflux forms a… under what reagent and conditions observation?
Carboxylic acid reagent: acidified potassium dichromate conditions: reflux observation: orange to green
Ethanol oxidised to ethanoic acid equation
CH3CH2OH + 2[O] –> CH3COOH +H2O
Ethanal oxidised into ethanoic acid equation
CH3CHO + [O] –> CH3COOH NO WATER MADE
Why is reflux used to oxidise an alcohol into a carboxylic acid?
reflux doesn’t allow any reactant vapour to escape.
Oxidation of secondary alcohol forms a… under what regent and conditions observation?
Ketone reagent: acidified potassium dichromate conditions: distillation or reflux observation: orange to green
Propan-2-ol oxidised to propanone equation
CH3CH(OH)CH3 + [O] –> CH3COCH3 + H2O
Test for aldehydes or ketones (silver mirror)
Tollens reagent warm gently Aldehyde: Silver mirror forms Ketone: NVC
Test for aldehydes and ketones (Fehling’s test)
Fehling’s solution warm gently Aldehyde: blue to brick red ppt Ketone: NVC
Test for carboxylic acid
Sodium carbonate effervescence