thermodynamics
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enthalpy of formation
the enthalpy change when one mole of a substance is formed from it’s elements with all reactants and products in their standard states (+/-)
enthalpy of combustion
the enthalpy change when one mole of a substance in it’s standard states is completely burned in oxygen (-)
enthalpy of atomisation (element)
the enthalpy change when one mole of gaseous atoms is formed from the element in it’s standard states (+)
enthalpy of atomisation (compound)
the enthalpy change when one mole of a compound in it’s standard state is converted into gaseous atoms (+)
first ionisation energy
the enthalpy change when one mole of gaseous atoms is converted into one mole of gaseous, singly charged positive ions (+)
2nd ionisation energy
the enthalpy change when one mole of gaseous, singly charged positive ions is converted into one mole of gaseous, doubly charged positive ions (+)
1st electron affinity
the enthalpy change when one mole of gaseous atoms is converted into one mole of gaseous, singly negative ions (-)
2nd electron affinity
the enthalpy change when one mole of gaseous, singly negatuve ions is converted into one mole of gaseous, doubly negative ions (+)
lattice dissociation enthalpy
the enthalpy change when one mole of an ionic compound is separated into gaseous ions (+)
lattice formation enthalpy
the enthalpy change when one mole of an ionic compound is formed from it’s gaseous ions (-)
enthalpy of hydration
the enthalpy change when one mole of gaseous ions is converted into one mole of aqueous ions (-)
enthalpy of solution
the enthalpy change when one mole of an ionic compound completely dissolves in water to give a solution of infinite dilution (-/+)
what is the equation for gibbs free energy
ΔG = ΔH - TΔS
enthalpy of neutralisation
enthalpy chnage when one mole of water is formed in reaction between an acid and an alkali under standard conditions
bond dissociation enthalpy
enthalpy change when one mole of covalent bonds is broken in the gaseous state
enthalpy of vaporisation
enthalpy change when one mole of a liquid is turned into gas
enthalpy of fusion
enthalpy chnage when one mole of a solid is turned into a liquid
enthalpy of formation exo or endo
exo
enthalpy of combustion exo or endo
exo
first electron affinity exo or endo
exo
second electron affinity exo or endo
endo
bond dissociation enthalpy exo or endo
endo
enthalpy of vaporisation exo or endo
endo
enthalpy of neutralisation exo or endo
exo