Glitter
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What is glitter?
• Not the same as shimmer • Synthetic multilayered particles - plastic or aluminium, or a hybrid • Cut from rolled sheets, tend to be hexagonal, square or rectangle, or a custom shape
Where can glitter be found?
• Decorative cosmetics • Sunscreens • Gel pens • Temporary tattoos • Glue • Paints • Woven in fabric
What is shimmer?
• Mainly mica based • Used on its own (pearlescent effects) • Used as a substrate then coated with various metal oxides
How are interference pigments made?
• Middle layer of mica (low refractive index) • Surrounded by metal oxide layer that has a high rerfractive index • Can be multilayered to give more discriminatory value • Thickness of metal oxide layers dictate colours reflected and transmitted
What are some alternative substrates to mica in interference pigments?
• Borosilicate glass, silica, alumina • Thinner and more uniform than natural mica • Colourless (mica is slightly yellow) • Lower RI than mica - increases interference
Glitter vs shimmer
• Glitter is synthetic, mica based shimmer is natural • Mica alone or coated with metal oxides never contains plastic, glitter almost always does (or is aluminium based) • Glitter will have identically shaped and sized particles, shimmer particles are irregular and randomly shaped and sized
What are some recovery considerations for glitter and shimmer?
• Should be analysed as multilayered paint flakes • Use a high intensity light source • Must not be lifted with J-Lar or acetate • Glass or plastic vial is best then a bag • Embedded particles must not be removed at scene • Dont refrigerate or freeze
What is the analytical workflow for glitter?
• gross examination, recovery, collection • preliminary evaluation of physical characteristics (microscopy of gauge) • physical fit - manufacturing defects • all microscopic techniques • microspectrophotometry • ATR infrared spectroscopy (plastic chemsitry) • specific gravity • raman micro spectroscopy (polymer layers) • SEM-EDX - elemental composition of layers
What should you look for with glitter evidence?
• Number of particles and their physical dimensions • Location of particles • Number, sequence, thickness and colour of layers • Manufacturing defects, weathering, delamination, corrosion, damage
What can manufacturing defects tell you?
• Probative value • Has the potential to match to a particular machine and so the manufactuer
What different analysis methods should be used when analysing glitter with microscope?
• Oblique or alternate lighting as particles reflect differently • Alternate between black, grey, and white backgrounds to facilitate colour determinations
What are benefits of glitter as trace evidence?
• highly individualistic - different shape, thickness, size, number, morphology • nearly invisible • high probability of transfer and retention • quickly collected, separated and concentrated • easily characterised • databsing capabilities • relatively persistent and resistant to degradation