5 QUALITATIVE ANALYSIS (QA)
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What salts Colour of solid : white Colour of aqueous salt solution : colourless
Smart People Constantly Make Amazing Zebra Art Sodium potassium calcium magnesium aluminium zinc ammonia
What salts Colour of solid : blue Colour of aqueous salt solution : blue
• CuSO₄: Copper(II) sulfate • Cu(NO₃)₂: Copper(II) nitrate
What salts Colour of solid : greeen Colour of aqueous salt solution :blue
CuCl₂: Copper(II) chloride
What salts Colour of solid : green Colour of aqueous salt solution ; insoluble
CuCO₃: Copper(II) carbonate
What salts Colour of solid : green Colour of aqueous salt solution : green
FeSO4, Fe(NO3)2, FeCl2 Iron sulfate Iron nitrate Iron chloride
What salts Colour of solid : brown Colour of aqueous salt solution : yellow
Fe₂(SO₄)₃ (iron(III) sulfate), Fe(NO₃)₃ (iron(III) nitrate), FeCl₃ (iron(III) chloride).
What salts Colour of solid : brown when hot and yellow when cold Colour of aqueous salt solution : insoluble
• PbO: Lead(II) oxide
What salts Colour of solid : black Colour of aqueous salt solution : insoluble
• CuO: Copper(II) oxide
What salts Colour of solid : yellow when hot and white when cold Colour of aqueous salt solution : insoluble
• ZnO: Zinc oxide
What salts Colour of solid : white Colour of aqueous salt solution : insoluble in cold water but soluble in hot water to give a colour less solution
• PbCl₂: Lead(II) chloride
What salts Colour of solid : yellow Colour of aqueous salt solution : insoluble in cold water but soluble in hor water to give a colour less solution
• PbI₂: Lead(II) iodide
All metal hydroxides, except for which grp hydroxides, are insoluble?
grp 1
how to test for cations Ca2+, Zn2+, Al3+, Pb2+, Fe2+, Fe3+,Cu2+ , NH4
Reagent (NaOH(aq) / NH3(aq)) must be added drop-wise, then in excess. If precipitate forms, the colour of precipitate must be noted and the solubility of precipitate in excess alkali must be checked.
Ca2+ -> NaOH(aq) tests reactions
dropwise: white ppt formed excess: white ppt insoluble in excess
Zn2+ -> NaOH(aq) tests reactions
dropwise:white ppt formed excess:white ppt soluble to give colourless solution
Al3+ -> NaOH(aq) tests reactions
dropwise:white ppt formed excess:white ppt soluble to give colourless solution
Pb2+ -> NaOH(aq) tests reactions
dropwise:white ppt formed excess:white ppt soluble to give colourless solution
Fe3+ -> NaOH(aq) tests reactions
dropwise:reddish-brown ppt formed excess:reddish-brown ppt insoluble in excess
Fe2+-> NaOH(aq) tests reactions
dropwise:green ppt formed excess:green ppt insoluble in excess
Cu2+ -> NaOH(aq) tests reactions
dropwise:blue ppt formed excess:blue ppt insoluble in excess
NH4+ -> NaOH(aq) tests reactions
dropwise: no ppt formed excess: NA UPON HEATING: Colourless and pungent gas was evolved which turned the damp red litmus paper blue. Gas evolved is NH3(g). (difference between this and NO3- is no aluminium foil)
cation NaOH memory tech
dropwise: first 4 is white ppt formed, then rgb and no ppt excess. first insoluble, next 3 white soluble to colourless(ZAP), rest insoluble
Ca2+-> NH3(aq) tests reactions
dropwise: no ppt formed excess: NA
Zn2+-> NH3(aq) tests reactions
dropwise:white ppt formed excess:white ppt soluble to give colourless solution