Inorganic 1 Section 2 - Unit 10: Halogens
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State the equation for the reaction between chlorine and water (1 mark)
• Cl2 + H2O → HOCl + HCl
When a pool has a pH of over 7.0, explain how adding chlorine to water affects the equilibrium (2 marks)
• Alkaline ions react with acid - So equilibrium shifts to the right
Explain why chlorine is used to kill bacteria in swimming pools, even though chlorine is toxic (2 marks)
• Only used in small amounts - Health benefits outweigh the risk
Which substance reacts most rapidly to produce a silver halide precipitate with acidified silver nitrate?
• CH3l
Explain why chlorine has a lower boiling point than bromine (1 mark)
• Chlorine is smaller than bromine - Cl2 has weaker intermolecular forces
State how you could tell the difference between AgBr and AgI (3 marks)
• Concentrated ammonia • Cream solid dissolves • Yellow solid does not dissolve
Describe fluorine (1)
• Pale yellow gas
Describe chlorine (1)
• Greenish gas
Describe bromine (2)
• Red liquid - Gives off brown/orange poisonous fumes
Describe iodine (2)
• Shiny grey solid - Purple gas
Explain why melting and boiling point increases down the halogen group (3 marks)
• Down the group, more electrons • So larger VDW • So more energy required to break the forces
Role of H₂SO₄ when reacting with NaF and NaCl (1 mark)
• Acid
Role of H₂SO₄ when reacting with NaBr and NaI (2 marks)
• Acid in first step - Then oxidising agent
Appearance of HI (1 mark)
• White steamy fumes
Appearance of SO₂ (1 mark)
• Colourless acidic gas
Appearance of H₂S (1 mark)
• Gas with bad egg smell
Equation for reaction of NaF with H₂SO₄ (1 mark)
NaF (s) + H₂SO₄ (l) —> NaHSO₄ (s) + HF (g)
Observation for reaction of NaF with H₂SO₄ (1 mark)
White steamy fumes of HF
Equation for reaction of NaCl with H₂SO₄ (1 mark)
NaCl (s) + H₂SO₄ (l) —> NaHSO₄ (s) + HCl (g)
Observation for reaction of NaCl with H₂SO₄ (1 mark)
White steamy fumes of HCl
Explain why redox reactions do not occur with NaF and NaCl with H₂SO₄ (2 marks)
• F- and Cl- are not strong enough reducing agents - So cannot reduce the S in H₂SO₄
Equation for acid-base step of reaction of NaBr with H₂SO₄ (1 mark)
NaBr (s) + H₂SO₄ (l) —> NaHSO₄ (s) + HBr (g)
Equation for redox step of reaction of NaBr with H₂SO₄ (1 mark)
2H+ + 2Br- + H₂SO₄ –> Br₂ + SO₂ + 2H₂O
Overall equation for reaction of NaBr with H₂SO₄ (1 mark)
2NaBr + 3H₂SO₄ –> 2NaHSO₄ + Br₂ + SO₂ + 2H₂O