Alkanes
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Define alkanes.
Compounds containing only C-C and C-H single bonds
What is the general molecular formula for alkanes?
CnH2n+2
What is the general formula for cycloalkanes?
CnH2n
What is each successive member of a homologous series called?
a homologue
What is the repeating unit for alkanes?
CH2
What is CH2 called?
Methylene group
How does each homologue in the alkane series differ from one another?
Each homologue has one more C atom than the preceding member
What is a methylene group?
CH2
Are alkanes and cycloalkanes saturated or unsaturated?
They are saturated
What does saturated mean?
They contain the maximum number of H per C and have no double or triple bonds
What is the definition of a homologous series (in terms of alkanes)? (5)
Molecules that have the same general formula Homologues differ by CH2 Contain the same functional group Show gradation in physical properties as molar mass increases Homologues can be prepared by similar methods
What are branched alkanes?
Alkane molecules that have more than three C atoms that can be arranged in more than one way
How many C atoms are needed in order for an alkane to be branched?
Three
Give an example of an alkane that has a branched form.
Butane
What is the branched form of butane?
Isobutane
Describe the structure of isobutane.
2, methylpropane A methyl branch exists off the second carbon in the longest chain
In general when is ‘iso’ used in relation to branched alkanes?
When there is one methyl group attached to the longest carbon chain
In general when is ‘neo’ used in relation to branched alkanes?
When there is two methyl groups attached to the carbon chain
What is an unbranched alkane often called? 3
An n-alkane A normal alkane An unbranched alkane
How many structural isomers does pentane have?
Three
List the three structural isomers of pentane.
Pentane Methylbutane / isopentane Dimethylpropane / Neopentane
What is methylbutane more commonly called?
Isopentane
What is dimethylpropane more commonly called?
Neopentane
What is nomenclature?
The naming of organic compounds