3.1.2 group 2
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Atom radius
Increases down the group Atoms have more electron shells
Melting points
Decreases down the group Metallic bonding weakens as atomic size increases Distance between positive ions and delocalised electrons increases So, electrostatic forces between positive ions and delocalised electrons weakens
Second ionisation energy
enthalpy change when one mole of gaseous ions with a single positive charge forms one mole of gaseous ions with a double positive charge Ti+(g) > Ti+2(g) + e-
Reactivity
Increases down the group As atomic radius increases there is more shielding Nuclear attraction deceases and it is easier to remove outer electrons Cations form more easily
Reactions with oxygen
Burn in oxygen Mg burns with bright white flame - MgO is a white solid
Reactions with water
Produces oxide and hydrogen
Reactions with warm water
Hydroxide + hydrogen Makes water alkaline
Reactions with warm water observations
Fizzing - more vigorous down group Metal dissolving - faster down group Solution heating up - more down group With calcium - white precipitate appearing
Reactions with acid
Form salt and hydrogen
Metal Oxide + water
Hydroxide formed of varying solubility
2 important
Milk of magnesia - used as medicine (Mg(OH)2) Calcium hydroxide - used in agriculture to neutralise acidic soils
Test for CO2
calcium hydroxide (lime water) Limewater turns cloudy as white calcium carbonate is produced Ca(OH)2 + CO2 > CaCO3 + H2O