qualitative analysis
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adding sodium hydroxide and aqueous ammonium solution to ammonium
ammonia gas produced on warming
adding sodium hydroxide and aqueous ammonium solution to copper (II)
light blue ppt insoluble in excess light blue ppt dissolves in excess ammonia, giving deep blue solution
adding sodium hydroxide and aqueous ammonium solution to iron (II)
green ppt insoluble in excess
adding sodium hydroxide and aqueous ammonium solution to iron (III)
rust brown ppt insoluble in excess
adding sodium hydroxide and aqueous ammonium solution to chromium (III)
grey green ppt, soluble in excess giving a green solution grey green ppt insoluble in excess
adding sodium hydroxide and aqueous ammonium solution to calcium
white ppt insoluble in excess no ppt/very slight white
adding sodium hydroxide and aqueous ammonium solution to magnesium
white ppt insoluble in excess
adding sodium hydroxide and aqueous ammonium solution to zinc
white ppt soluble in excess giving a colourless solution white ppt insoluble in excess
adding sodium hydroxide and aqueous ammonium solution to aluminium
white ppt soluble in excess giving a colourless solution white ppt insoluble in excess
NA+ (cations)
colourless in solution golden yellow in flame
K+ (cations)
Colourless in solution Lilac in flame
CA 2+ (cations)
colourless in solution orange-red in flame
sr 2+ (cations)
colourless in solution crimson-red in flame
ba 2+ (cations)
colourless in solution apple-green in flame
mg 2+ (cations)
colourless in solution bright-white in flame
cu 2+ (cations)
blue in solution green in flame
carbonate (anion test)
add dilute HCL fizzing, co2 produced
chloride, bromide, and iodide (anion test)
acidify with dilute HNO3 then add aq AGNO3 chloride: white ppt soluble in ammonia bromide: off white ppy, slightly soluble in ammonia iodide: yellowish-white ppt insoluble in ammonia
sulfate (anion test)
acidify with dilute HCL/HNO then add aq BaCL2/ Ba(OH)3 white ppt of barium sulfate
nitrate (anion test)
mix sodium alkaline with NAOH then add Al foil and warm slightly red litmus turns blue
ammonia (gas test)
colourless, pungent smell hold damp red litmus in the gas indicator paper turns blue
chlorine (gas test)
pale green choking smell hold damp litmus paper in gas paper is bleached to white
carbon dioxide (gas test)
colourless and odourless pass gas through limewater limewater turns milky due to presence of CACO3
sulfur dioxide (gas test)
colourless acidic/pungent smell add to solution of filter paper soaked in potassium manganate (VII) potassium manganate changes from purple to colourless