acids and bases 3.1.12 in papers 1+3
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whats an acid?
proton donator
whats a base?
proton acceptor
how do weak and strong acids dissociate?
• strong acids completely dissociate • weak acids partially dissociate
what is pH?
-log10[H+]
how do you calculate [H+]?
10^-pH
what does increasing the concetration of H+ ions do?
decreases the pH
what is the ionic product of water?
kw= [OH-][H+]
whats the effect of kw as tempreture increases?
increases
what is ka?
dissociation constant for a weak acid
whats the ka expression?
[H+][A-] ——.———- [HA]
how do you calculate pka?
-logka
how do you calculate ka?
10^-pka
how do you calculate [H+] of pure water?
square root kw
how do you calculate [H+] of a weak acid?
square root of ka x its concentration
how do you calculate [H+] at 1/2 equivilance point?
ka
how do you calculate [H+] of an acidic mixture?
n(left over H+ ions) ——-.———————— total volume
how do you calculate [H+] of an alkaline mixture?
kw —.—– ( n(left over OH- ions) —-.—————————- new total volume
what is the equivilance point?
• acid and alkali react as per their balanced equation • salt and water is left over
why does a pH titration curve start with a straight line?
[H+] wouldnt stay constant
how to choose a suitable indicator?
• one that changes rapidly during titration • indicator range must fall into pH range
what is a buffer solution?
a solution that resits a change in pH when small amounts of an acid or an alkali are added?
what is an acidic buffer made of?
weak acid + its salt
what is a basic buffer made of?
weak base + its salt
what happens when you add an acid to an acidic buffer?
• equilibrium shifts to the left to counteract increase in H+ • removing added H+