2.5 Organic Chemistry
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Carbon introduction
Can form four covalently bonds, which can form chains when bonded to each other There is a large number of carbon compounds which can be simplified by grouping them into a homologous series
Homologous series
A family of organic compounds where members have the same general formula, show similar chemical properties, show a graduation in their physical properties and differ by a CH2 group
Hydrocarbon
Compound/molecule consisting of hydrogen and carbon only
Crude oil
Finite resource, main source/mixture of hydrocarbons and a feedstock for the petrochemical industry
How can crude oil be removed from the Earth
Drilling
Fraction
Largely a mixture of compounds of formula CnH2n+2, which are members of the alkane homologous series (eg alkanes are obtained from crude oil)
Fractional distillation
Separation of a liquid mixture into its different compounds by boiling and condensing at different boiling points
How does fractional distillation work
As the gases move up the column, hydrocarbons condense when the temperature of the column is the same as their boiling point
Use of refinery gases
Bottled gases
Use of petrol
Fuel for cars
Use of naptha
Manufacture chemicals and plastics
Use of kerosene
Fuel for aircraft
Use of diesel oil
Fuel for cars and frains
Use of fuel oil
Fuel for ships and central heating
Use of bitumen
Surface roads and roofs
What increases as you move down the fractioning column
Boiling point, number of carbon atoms, size of hydrocarbons
Order of fractions obtained from fractioning column
Refinery gases, petrol, naptha, kerosene, diesel oil, fuel oil, bitumen
Environmental concerns of crude oil
Transport of crude oil and result in spills and leakages Drilling for oil in the sea bed can result in leaks Air pollution is caused by burning fossil fuels as carbon dioxide is released
Cracking
Breakdown of larger saturated hydrocarbons (alkanes) into smaller more useful ones, some of which are unsaturated (alkenes)
Use of alkenes produced from cracking
Petrochemical industry to synthesise polymers and pharmaceutical drugs
General formula of alkanes
CnH2n+2
Methane
CH4
Ethane
C2H6
Propane
C3H8