Organic Chemistry
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Crude oil
A mixture of different hydrocarbons Formed from the remains of plankton that died millions of years ago and got buried in mud
Uses of crude oil
Plastic Petrol Pharmaceuticals Cosmetics
Hydrocarbon
Made of hydrogen and carbon atoms
Alkane
A type of hydrocarbon Carbon surrounded by hydrogen with single bonds
General formula for alkanes
Cn H2n+2
Why are alkanes saturated molecules?
Because carbon can only have 4 bonds And in alkanes they are fully bonded with single molecules showing they have the maximum number of hydrogens possible
Viscosity
Thickness of a fluid High viscosity = thick and doesn’t flow easily Low viscosity = think and flows easily
Properties of long chain hydrocarbons
Viscos/ think (flows slowly) Less flammable High boiling point (requires more energy to overcome bonds)
Properties of short chain hydrocarbons
Not viscos (Thin) flows easily Flammable Low boiling point (not much energy required to break bonds)
How does properties of hydrocarbons change?
When written all down, they change proportionally going up or down Eg going up they increase in viscosity
How are hydrocarbons used for fuels?
Alkanes are combusted ie burnt
What does complete combustion of alkanes release?
Carbon dioxide and water
Fractional distillation
Separating crude oil into ‘fractions’ in a column Depending in their chain length eg long chain or shirt chain thus their properties Done so we can use the different hydrocarbon lengths for different purposes
How does fractional distillation work?
Crude oil heated and becomes a gas Enters the column, where it’s hot at the bottom and cool at the top As the gas rises up the column, different hydrocarbons will reach their boiling point at different points The long ones reach it at the hot bottom so they condense there and leave Short ones condense into liquid at the top and leave Very short ones remain as gases and leave
Long chain hydrocarbon uses
Fuel for ships and power stations Bitumen/ asphalt for roads Diesel
Short chain hydrocarbon uses
Fuel for aircraft Petrol Fuel for house cooking
Cracking
Process of breaking long chain hydrocarbons to be shorter As shorter ones are more flammable and easier use for fuel This does not involve crude oil. ONLY HYDROCARBONS
What are the products of cracking?
A short chain alkane and an alkene
Conditions for catalytic cracking
Very high temperature Catalyst to speed it up
Steam cracking conditions
Very high temp Steam
Alkene
Type of hydrocarbon with 1 double covalent bond between 2 carbon atoms
Alkene general formula
Cn H2n
Are alkenes saturated?
No. Because they have 2 less hydrogen molecules than the corresponding alkane they possibly can have
Does methene exist?
No because there must be a double bond between 2 carbon atoms But meth- only has 1 carbon atom so it’s not possible