transition metals and reaction of aq ions
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adsorption
the process of forming weak bonds by reactants to the surface of a solid catalyst
autocatylsis
a reaction where the product of a reaction acts as a catalyst for the reaction
Bidentate ligand
ligand that can form two co-ordinate bonds
Calibration curve
used in colorimetry to plot the amount of absorbance vs concentrations of standard solutions. This is then used to measure the concentration of an unknown solution of your transition metal ion
Catalyst poisoning
Impurities in a reaction mixture may bind to a heterogeneous catalyst’s surface and block reactants from being adsorbed.
Chelation
the process by which a multidentate ligand replaces a monodentate ligand in forming co-ordinate (dative) bonds to a transition metal ion
Cis-trans isomerism
A type of stereoisomerism. Octahedral complexes with four monodentate ligands of one type and two monodentate ligands of another type can show cis-trans isomerism. If the two odd ligands are opposite, it is the trans isomer. If the two odd ligands are next to each other, it is the cis isomer
Cisplatin
A transition metal compound which is used as an anti cancer drug. It has a square planar shape
Colorimeter
Instrument used in spectroscopy which calculates how much light is absorbed by the sample
Complex
A central metal atom or ion surrounded by coordinately bonded ligands
Contact Process
An industrial process used to produce sulfuric acid. Vanadium(V) oxide acts as a heterogeneous catalyst
Coordinate bond
is a covalent bond in which both electrons in the shared pair come from the same atom
Coordination number
The number of coordinate bonds that are formed with the central metal ion
Heterogeneous catalysts
A catalyst that is in a different phase from the reactants
Homogeneous catalysts
Catalysts that are in the same phase as the reactants - i.e. in the same physical state
Ligand
an atom, ion or molecule that forms a co-ordinate (dative) bond with a transition metal ion using a lone pair of electrons
Ligand substitution
A reaction in which a ligand is substituted by another ligand
Monodentate ligand
Ligands that can only form one co-ordinate bond
Multidentate ligand
Ligands that can form more than one co-ordinate bond
Optical isomerism
type of stereoisomerism which occurs when a substance exists in two forms that are non-superimposable mirror images. Complex ions can show optical isomerism when a central metal ion is coordinately bonded to three bidentate ligands
Redox titrations
A titration experiment to determine the concentration of an unknown solution by carrying out a redox reaction between the two reactants
Spectroscopy
A technique used to determine the concentration of a solution by measuring how much light it absorbs
Transition metal
A metal that can form one of more stable ions with a partially filled d sub-level
Variable oxidation states
Transition elements have variable oxidation states which means they can form ions with different oxidation states