Molecular shape and Bonding
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what is a non- polar covalent bond ?
_ Similar electronegativity
what is a polar covalent bond ?
• have dipoles • difference in electronegativity less than 2
what are 3 properties of ionic compounds ?
• highly ordered crystal lattice • conduct electricity when molten • high bp
what are electropositive elements ?
• elements with low ionisation energy (outer e- easily removed)
what are electronegative elements ?
• elements that readily acquire electrons
what are the factors affecting lattice energy ?
• ionic radius • ionic charge • no of shells /sheilding
How does ionic radius affect LE ?
• smaller ionic radius = greater attraction so higher LE
How does ionic charge affect LE ?
• greater ionic charge = greater attraction so higher lE
what is electronegativity ?
• the ability of an atom to pull bonding electrons towards itself
what are degenerate orbitals ?
• have same energy level • eg 2p orbitals
why do electrons in degenerate orbitlas occupy empty ones first ?
• to minimise repulsion
why is the 4s orbital filled before 3d ?
• it has a lower energy level
what is a radial node ?
• region where there is zero probability of finding an electron
what are 2 properties of 2p orbitals ?
• degenerate (same energy) • each orbital is perpendicular to the other two
what is the rule for molecular orbital theory ?
• number of AO = number of MO • always get a bonding and anti-bonding MO
what is a sigma bonding molecular orbital ?
• atomic orbitals of same phase sign overlap
what is anti-bonding molecular orbital ?
• atomic orbitals of opposite phase sign overlap
what is constructive combination ?
• wave function of e- are in the same phase
what is destructive combination ?
• wave function of e- are in opposite phases
what is the difference between anti bonding and bonding MO ?
• anti bonding has a node and no electrons • anti - bonding is higher in energy
What does end on overlap of 2p orbitals lead to ?
• sigma bonds
what does side on overlap of p orbitals lead to ?
• pi bonds
explain the hybridization of carbon for CH4 ?
• one e- from a 2s orbital is promoted to a spare p orbital • makes 4 degenerate sp3 orbitals • helps from 4 equivalent bonds
How are C-H bonds formed in ethane ?
• overlap of sp3 and hydrogen s orbital