Mechanism conditions
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Nucleophilic substitution
• warm/hot, ethanolic potassium cyanide • Warm aqueous sodium/ potassium hydroxide/ water, reflux • AgNO3- source of water • Warm, excess ethanolic ammonia
Elimination reaction
• Warm, hydroxide ions dissolved in ethanol • Reflux • Alkenes • Adjacent • Halogenoalkanes to alkenes
Electrophilic addition
• hydrogen halides • cold concentrated sulfuric acid, add cold water and warm the product to form an alcohol • Halogens • water in the form of steam, hot, concentrated phosphoric/sulfuric acid catalyst
Dehydration of alcohols
• Produces alkenes, sometimes a mixture with water • Concentrated sulfuric acid/ phosphoric acid an aluminium oxide catalyst/ acid catalyst
Hydration of alcohols
• Steam (300C), and acid catalyst (phosphoric (v) acid catalyst) • Reversible • Pressure 60atm
Free radical substitution reaction
• Alkanes to halogenoalkanes • U.V light • Chlorine radical and bromine radical • Chain reaction
Oxidation reaction
• Primary alcohols to aldehydes • Secondary alcohols to ketones • Aldehydes to carboxylic acid under reflux (acidified potassium dichromate)
give a reagent for an elimination reaction
dehydration or elimination 1 (conc) H2SO4 or (conc) H3PO4 allow dilute and Al2O3 Do not allow iron oxides