Alcohol
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Conditions for the hydration of ethene by steam
300 degrees 60 atm Phosphoric Acid Catalyst
What is a renewable source for when ethene runs out?
Ethanol
What is the chemical equation for ethanol from fermentation?
C6H12O6 –> 2C2H5OH + 2CO2
Is fermentation endothermic or exothermic?
Exothermic
What enzyme does fermentation of glucose require? What is the temperature optimum?
30-40 degrees Yeast
Does fermentation use anaerobic or aerobic conditions?
Anaerobic
After forming, what happens to ethanol before use as a biofuel? Why?
Fractional distillation To rid of the rest of impurities
How can alcohols be produced other then fermentation?
By hydration of an alkene with an acid catalyst.
Does hydration or fermentation have a higher percentage yield?
Hydration - produced only ethanol. Fermentation - produces CO2 as well
Is hydration or fermentation cheaper?
Fermentation Required a lower temperature so cheaper tools
Is hydration or fermentation slower?
Fermentation Has to be made in batches whilst hydration can done industrially
Is hydration or fermentation more renewable?
Fermentation Uses renewable sources
Is hydration or fermentation faster?
Hydration Fermentations requires fractional distillation afterwards
What is a biofuel?
A fuel made from from recently deceased biological molecules
Why is biofuel good?
Renewable & Sustainable Classified as carbon neutral
Why is biofuel bad?
Petrol cars have to be modified to accommodate Takes up land for growing crops for ethanol instead
What are the equations showing biofuel as net zero?
Plants take in CO2: 6CO2 + 6H20 -> C6H12O6 + 6O2 Fermentation, glucose into ethanol: C6H12O6 -> 2C2H5OH + 2CO2 Ethanol burnt and CO2 produced again: 2C2H5OH + 6O2 -> 4CO2 + 6H2O
Why is the net zero classification not entirely accurate?
Make fertilisers for the crops Harvest the crops Refine the crops Transport the crops
What oxidant agent is used for alcohol? Chemical formula?
Potassium dichromate K2Cr2O7
Oxidation of a primary alcohol
Aldehyde -> Carboxylic acid
Oxidation of a secondary alcohol
ketone
Oxidation of a tertiary alcohol
No reaction
How to collect an aldehyde before it oxides into carboxylic acid?
Distillation Excess of alcohol
How to collect carboxylic acid?
Reflux Excess of oxidising agent