reaction pathways of aliphatic compounds
No description yet. This curated deck is ready for daily study.
Card preview (24)
alkane -> haloalkane
• conditions: halogen, UV radiation • reaction: free radical substitution (learn steps) • NOP: HX (g)
alkene -> alkane
• conditions: H₂ / Ni • reaction: hydrogenation (addition)
alkene -> dihaloalkane
• conditions: X₂ • reaction: halogenation (addition) • electrophilic addition (know mechanism)
alkene -> alcohol
• conditions: H₂O (steam) / H₃PO₄ • reaction: hydration (addition), 2 possible products
alkene -> haloalkane
• conditions: hydrogen halide • reaction: electrophilic addition (know mechanism)
haloalkane -> alcohol
• conditions -: NaOH (aq) • reaction: nucleophilic substitiution (hydrolysis, know mechanism) • NOP: X-
haloalkane -> amine
• conditions: NH₃ / ethanol, NaOH to liberate amine from salt • NOPs: NaCl + H₂O
haloalkane -> nitrile
• conditions: NaCN / ethanol • reaction: nucleophilic substitution (know mechanism) • NOP: X-
primary alcohol -> aldehyde
• conditions: K₂Cr₂O₇ / H₂SO₄, distillation • reaction: oxidation • NOP: H₂O
primary alcohol -> carboxylic acid
• conditions: K₂Cr₂O₇ / H₂SO₄, reflux • reaction: oxidation, have 2 [O] in equation • NOP: H₂O
secondary alcohol -> ketone
• conditions: K₂Cr₂O₇ / H₂SO₄, reflux • reaction: oxidation • NOP: H₂O
alcohol -> alkene
• conditions: H₃PO₄ or H₂SO₄, heat under reflux • reaction: dehydration (elimination)
alcohol -> haloalkane
• conditions: sodium halide / H₂SO₄, heated under reflux, which forms a hydrogen halide in situ • reaction: nucleophilic substitution (know mechanism) • NOP: H₂O
alcohol -> ester
• conditions: carboxylic acid / conc. H₂SO₄ OR acid hydride • reaction: esterification • NOP: H₂O
aldehyde -> primary alcohol
• conditions: NaBH₄ / H₂O • reaction: nucleophilic addition, reduction • 2 [H] in equation, know mechanism
aldehyde -> carboxylic acid
• condtions: K₂Cr₂O₇ / H₂SO₄, reflux • reaction: oxidation
aldehyde -> hydroxynitrile
• conditions: NaCN (aq) / H+ (aq) - these make HCN • reaction: nucleophilic addition (know mechanism)
ketone -> secondary alcohol
• conditions: NaBH₄ / H₂O • reaction: nucleophilic addition, reduction • 2 [H] in equation, know mechanism
ketone -> hydroxynitrile
• conditions: NaCN (aq) / H+ (aq) - these make HCN • reaction: nucleophilic addition (know mechanism)
aldehyde / ketone -> hydroxynitrile
• conditions: HCN • reaction: nucleophilic addition (know mechanism)
carboxylic acid -> carboxylate
• redox reactions with metals • neutralisation reactions with bases (alkalis, metal oxides, and carbonates)
carboxylic acid -> ester
• conditions: alcohol / conc. H₂SO₄ • reaction: esterification • NOP: H₂O
carboxylic acid -> acyl chloride
• conditions: SOCl₂ • NOPs: SO₂ (g), HCl (g)
carboxylic acid -> acid anhydride
• reactants: 2 CAs • NOP: H₂O