Organic analysis (chemical tests)
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what is the test for alkenes then result
• shake with bromine water • orange to colourless
What is the test for haloalkanes, then result
• add warm NaOH • add acidified AgNO3 • precipitate of AgX
result for Haloalkanes and how you’d tell the difference
• precipitate of AgX • chloro - white precipitate • bromo - cream precipitate • iodo - yellow precipitate
how to distinguish between the white,cream and yellow ppt
• chloro (white ppt) dissolves in dilute ammonia • bromo (cream ppt) dissolves in concentrated ammonia • Iodo (yellow ppt) doesn’t dissolve and there’s no visible change
what is the test for Alcohols, and what is the result
• add acidified potassium dichromate (K2Cr2O7) • orange to green (only primary and secondary)
what are the tests for aldehydes and the results
• warm with Fehling’s solution • Blue solution to red ppt • warm with Tollen’s solution • Silver mirror formed
what is the test for Carboxylic acids and the result
• add NaHCO3 • CO2 given off/fizzing/effervescence