Unit 4.5 Carboxylic Acids
No description yet. This curated deck is ready for daily study.
Card preview (24)
Weird starting?
I suppose
What is the pH of ethanoic acid?
3 pH
What is the pH of phenol?
5 - 6 pH
What is the pH of water?
It should be 7 pH
What is the pH of ethanol?
7.3 pH
How is an ethanoate ion created?
Ethanoic acid + water
Equation formula of the creation of ethanoate ion
CH3COOH + H2O ⇌ CH3COO- + H+/H3O+
How do acids tend to dissociate (2-way)
• When in water • liberating a hydrogen ion
How do u determine the strength of an acid? (1 additional thing)
• How well they dissociate in H2O • The more H+(aq) ions dissociated = strong acid
Explain stabilisation of ethanoate ion? (3-way)
• More stable than phenoxide ion • as negative charge can be delocalised • over the 2 equivalent oxygen atoms
Equation of ethanoate ion stabilisation? (might be asked to draw, so get whiteboard)
H3C(=O)O- <-> H3CO-(=O) -> H3CO–O (- in between o’s) Highly refer to booklet
Explain stabilisation of phenoxide ion? (2-way + 2-way)
• Stabilised through resonance of the negative charge • through the ring system • Less stable than ethanoate • as the resonance structures aren’t equivalent
Explain stabilisation of ethanol? (2-way + 2-way)
• Very little tendency for ethanol, • to give away the proton • No resonance structures possible • to support the negative charge
Ethanoic acid rxn with sodium hydroxide? (2 things)
• Reacts • Acid neutralised to form a salt
Ethanoic acid rxn with metal carbonate? (2 things)
• Reacts • Formation of CO2 gas (effervescing)
Phenol rxn with sodium hydroxide? (2 things)
• Reacts • Acid neutralised to form a salt
Phenol rxn with metal carbonate?
No reaction.
Ethanol rxn with sodium hydroxide?
No reaction.
Ethanol rxn with metal carbonate?
No reaction.
What is the equation for the formation of a carboxylic acid from a primary alcohol? ([O]-> means oxidation)
H3CCH2OH [O]-> H3CCOH [O]-> H3CCOOH
What’s an oxidant that can oxidise primary alcohols to a carboxylic acid?
Acidified potassium dichromate
Chemical formula for acidified potassium dichromate?
H+/K2Cr2O7
What is the colour change observation of the formation of a carboxylic acid from a primary alcohol?
Orange to green
But what are primary alcohols usually form into after being oxidised? (2 things)
• Aldehydes • Carboxylic acids