Oxygen (Descriptive Chemistry)
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What are the major allotropes of oxygen?
Dioxygen (O₂) and ozone (O₃)
What is the lab preparation of oxygen using hydrogen peroxide?
Decomposition of hydrogen peroxide with manganese dioxide catalyst: 2H₂O₂ → 2H₂O + O₂
What is the industrial method for oxygen production?
Fractional distillation of liquid air.
Uses of oxygen?
Respiration + life support systems Welding and cutting metals Rocket fuel oxidizer Steel manufacturing
What are the 4 main types of oxides?
Acidic oxides Basic oxides Amphoteric oxides Neutral oxides
What are acidic oxides? Give examples.
Non-metal oxides that react with bases to form salt + water. Examples: SO₂, CO₂, NO₂, P₄O₁o
What are basic oxides? Give examples.
Metal oxides that react with acids to form salt + water. Examples: Na₂O, CaO, MgO
What are amphoteric oxides? Give examples.
Oxides that react with both acids and bases. Examples: Al₂O₃, ZnO, PbO
What are neutral oxides? Give examples.
Oxides that do not react with either acids or bases. Examples: CO, NO, N₂O
What is ozone?
A triatomic allotrope of oxygen (O₃). Pale blue gas with a strong smell
How is ozone formed in the atmosphere?
O₂ + UV light → 2O O + O₂ → O₃
What are the properties of ozone?
Powerful oxidizing agent Toxic in high concentrations Unstable, decomposes to O₂
Uses of ozone?
Water purification Bleaching agent Air sterilization
What is the role of ozone in the stratosphere?
Absorbs harmful UV radiation, protecting life on Earth
What is a peroxide?
An oxide containing the O₂²⁻ ion (where each oxygen has a −1 charge). There are bonds between atoms of oxygen in between the element and oxygen. (Ba2O2, H2O2)
How are peroxides formed?
Typically, by reacting alkali metals (like Na, K) with excess oxygen. Example: 2Na + O₂ → Na₂O₂
What is a superoxide?
Contains the O₂⁻ ion, where oxygen has a −½ oxidation state
How are superoxides formed?
Formed when alkali metals react with excess oxygen under high pressure. Example: K + O₂ → KO₂
What are suboxides?
Oxides where the metal-to-oxygen ratio is unusually high – less oxygen than expected. These are often non-stoichiometric compounds.
Example of a suboxide?
C₃O₂ (carbon suboxide), Cu₄O₃ (copper suboxide)
What are mixed oxides?
Compounds that contain more than one oxidation state of the same element bonded with oxygen
Example of a mixed oxide?
Fe₃O₄ (contains Fe²⁺ and Fe³⁺), Pb₃O₄
What are normal oxides?
Oxides that contain oxygen in the typical −2 oxidation state. Example: H₂O, CO₂, MgO
How to identify oxide type by oxygen’s oxidation state?
Normal oxide: O²⁻ → oxidation state = −2 Peroxide: O₂²⁻ → each O = −1 Superoxide: O₂⁻ → each O = −½ Mixed/Suboxides: weird ratios or mixed oxidation states