Nutrition
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CHNOPS (96% of life)
Carbon Hydrogen Nitrogen Oxygen Phosphorus Sulfur
H2O (essential for life)
• Structure! • H2O (polar) • Oxygen’s electronegativity (electron pull) makes it partially negative and hydrogen partially positive. • These opposing charges create a hydrogen bond between individual water molecules.
4 properties that make H2O essential for life
Cohesive behavior (+ adhesion) Transpiration pull Surface Tension Ability to moderate temperature High specific heat: 4.184J or 1C per gram/1 degree Celsius. Evaporative cooling Expansion upon freezing Versatility as a solvent Polar (hydrophilic) vs. Nonpolar (hydrophobic)
Acid
substance that causes an increase in the relative number of H+ ions in solution
Base
substance that causes an increase in the relative number of OH- ions in solution
strong acids/bases
HCl and NaOH, reaction in water is not reversible.
weak acids/bases
H2CO3 and NH3, reaction in water is reversible (can reassociate H+ and OH- ions) Weak acids and bases can be used to regulate pH
pH scale (pouvoir hydrogene- hydrogen power)
the negative logarithm of the concentration of hydrogen ions in moles/liter pure water = 1/10,000,000 moles of hydrogen ions 0.0000001 mole per liter 10-7 mole per liter pH 7 neutral state
buffers
combinations of H+ donor and H+ acceptor forms of weak acids/bases H2CO3 (carbonic acid) -HCO3- (bicarbonate) used to regulate blood pH. Carbonic acid – bicarbonate buffering system
tetravalence
The ability to bond with 4 other atoms. Can create a wide variety of molecules. Structure influences function
organic chemistry
branch of chemistry that specializes in the study of carbon compounds (organic)
hydrocarbons
Hydrocarbons are organic molecules consisting of only carbon and hydrogen Many organic molecules, such as fats, have hydrocarbon components Hydrocarbons can release a large amount of energy
carbon backbone
arrangement of carbon atoms determines properties/functions Isomers structural, geometric (cis-trans), enantiomers
Organic Compound Functional Groups
Involved in chemical reactions Hydroxyl Alcohols, i.e. ethanol Carboxyl Carboxylic acids, ie. Acetic acid Amino Amines, i.e. glycine Sulfhydryl Thiols, i.e. ethanethiol Phosphate Organic phosphates, i.e. glycerol phosphate Carbonyl Ketones, i.e. acetone Aldehydes,i.e. propanol
polymer
large molecule consisting of many identical/similar building blocks (monomers)
monomer
hydrolysis reaction Addition of H2O breaks bonds between monomers condensation/dehydration reactions Removal of H2O creates bonds between monomers to build dimers and polymers.
The Diversity of Polymers
Each cell has thousands of different macromolecules They vary among cells of an organism, members of a population, and between species. Can built from a small set of monomers
monosaccharides (ready energy)
(CH2O) hydroxyl and aldehyde/ketone group produce ring structure (alpha or beta)
disaccharides (transport form)
formed through synthesis of 2 monosaccharide molecules by a glycosidic bond.
polysaccharides (storage/structural)
food storage starch (plants); glycogen (animals); alpha glycosidic bonds
structural polysaccharides
cellulose: major structural molecule in plants (beta glycosidic bonds) chitin: modified polysaccharide, found in the exoskeleton of insects and cell walls of fungi.
lipids
Fats Oils Waxes
fats and oils (energy in storage)
3 fatty acid joined to glycerol by an ester bond. Hydrophobic (nonpolar) CHO Lots of bonds = lots of stored energy saturated vs. unsaturated
Hydrogenation
Hydrogenation is the process of converting unsaturated fats to saturated fats by adding hydrogen Hydrogenating vegetable oils also creates unsaturated fats with trans double bonds