Thermodynamics
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1st electron affinity meaning
Enthalpy change when each atom in one mole of gaseous atoms gains one electron to form one mole of gaseous 1- ions
Enthalpy of atomisation meaning
Enthalpy change when one mole of gaseous atoms is produced from an element in its standard state
Hydration enthalpy meaning
Enthalpy change when one mole of gaseous ions become hydrated
Enthalpy of solution meaning
Enthalpy change when one mole of an ionic solid dissolves in an amount of water large enough so that the dissolved ions are seperated and do not interact with one another
Bond dissociation enthalpy meaning
Enthalpy change when one mole of covalent bonds is broken in the gaseous state
Lattice enthalpy of formation meaning
Enthalpy change when one mole of a solid ionic compound is formed from its constituent ions in the gas phase
Lattice enthalpy of dissociation meaning
Enthalpy change when one mole of a solid ionic compound is borken up into its constituent ions in the gas phase
Enthalpy of vaporisation meaning
Enthalpy change when one mole of liquid is turned into a gas
Enthalpy of fusion meaning
Enthalpy change when one mole of a solid is turned into a liquid
Enthalpy of formation meaning
Ethalpy change when one mole of a substance is formed from its constituent elements with all elements in standard states
Enthalpy of combustion meaning
Enthalpy change when one mole of a substance undergoes complete combustion in oxygen with all substances in standard states
Enthalpy of neutralisation meaning
Enthalpy change when 1 mole of water is formed in a reaction between an acid and alkali under standard conditions
First ionisation enthalpy meaning
Enthalpy change when each atom in one mole of gaseous atoms gains one electron to form one mole of gaseous 1+ ions
Enthalpy of solution triangle
Ionic solution into its constituent dissolves ions with the gaseous ions pointing upwards towards the respective substances
Process of born haber cycles and why
Enthalpy of formation - start and normally x Atomisation of solid - to turn it into a gas Atomisation of gas - to turn it into a gaseous atom/s Ionisation enthalpy/ies of solid - gain a positive charge equal to standard charge Electron affinity/ies of gas - gain a negative charge equal to standard charge Enthalpy of formation - downwards arrow with negative value OR Enthalpy of dissociation - upwards arrow with positive value
What does perfect ionic model mean?
Ions are perfect spheres
Explain why the second electron affinity of oxygen has a positive value [1]
[1] O- repels the electron
Explain why the enthalpy of dissociation for sodium oxide is greater than the enthalpy of lattice dissociation for sodium chloride [2]
[1] Oxide ions have a higher negative charge [2] Stronger attraction between oppositely charged ions
Why do data books not contain a value for the enthalpy of solution for sodium oxide? [1]
[1] Reacts with water
What is entropy?
Disorder
What is entropy directly proportional to?
The more disordered something is
Entropy units
J mol-1 k-1
Which state has the most and least entropy?
Gas has the most entropy. The particles move rapidly & randomly. Solids have the least entropy. The particles vibrate in a fixed position.
How does temperature affect entropy?
Higher temperature means faster moving particles and so higher entropy