Equations for All Papers
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Equation for: Relative atomic mass
((Isotopic mass x % abundance) + (Isotopic mass x % abundance) + (….)) / sum of all % abundance (% abundance can be substitued for relative intensity)
Equation for: Moles = (Basic Equation)
Mass / Mr Mass is in grams
Equation for: Percentage Error =
= uncertainty / (measurement or reading) One measurement is two readings, e.g. temperature is a reading but length is a measurement
Equation for: Concentration (moldm^(-3)) =
moles / volume (dm^3)
Equation for: Ideal Gas Equation
PV = nRT P= pressure (in Pa) V= Volume (in m^3) n= number of moles R= gas constant (8.31) T= temperature (K)
Equation for: Molar gas volume (used at Room Temperature)
moles = volume (dm^3) / 24
Equation for: % Yield
(Actual Yield / Theoretical Yield ) x100
Equation for: Atom Economy
( Mr useful products/ Mr of all products ) x100
Enthalpy Change Calculations - Using Enthalpy of Formation For Energetics and Thermodynamics
Sum of Products - Sum of reactants
Enthalpy Change Calculation - Calorimetry
q = mc ^ T q = heat given out (J) m = mass (g) c =Specific heat capacity (J/g/K) ^T = Temperature rise (K)
Enthalpy Change per mole Calcualtion - Calorimetry
q / number of moles reacting
What is the Equation for Kc?
when aA + bB -> cC + dD, then: Kc = [C]^c x [D]^d/ [A]^a x [B]^b
Equation for Acceleration (Mass Spectrometry)
KE = 1/2mv^2 when: * KE = kinetic Energy of Ion (Joules) * m = mass of one ion (Kg) * v = velocity of the ion (in m/s)
Entropy Change Calculations
Entropy = Products - Reactants
Gibbs Free Energy Change Calculations
^G = ^H -T^S when ^G < 0 a reaction is feasible Draw Gibbs graphs, y= mx+c
Equation for: Reaction rate (involving k)
reaction rate = k [a]^n where n is the order and [A] is concentration
State: Arrhenius equation
k = Ae ^(-Ea/RT) where k = rate constant A= arrhenius constant Ea = Activation energy (J) R= Gas Constant T = Temperature (K)
Equation for: Partial Pressure of gases p(A) Topic 19
= mol fraction (nA) x total pressure (Ptot)
Equation for Mole Fraction Topic 19
number of moles of gas A/ number of all moles of gas
Equation for: Kp when: A(g) + B(s) -> C(g) + 2D(g)
p(C) x p(D)^2 _______________ p(A)
Equation for: Energy Gap - Equation 1 (Transition Metals) When given: -planks constant (h) -velocity of light (c) -wavelength of light (l)
= Planks constant x Velocity of light ________________________ Wavelength of light
Equation for: Energy Gap - Equation 2 (Transition metals) when given: -planks constant (h) -frequency of light (v)
planks constant x frequency of light
Equation for: Kw =
Kw= [H+] x [OH-]
Equation for pH
pH = -log[H+]