organic reactions summary
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reagents, conditions, mechanism for alkane to halogenoalkane?
• Br2 or Cl2 • UV light • free radical substitution
conditions for thermal cracking?
• temp of 450-900 degrees celsius • pressure of 70 atm
conditions for catalytic cracking?
• temp of 400 degress celsius • slight pressure of 1-2 atm • zeolite catalyst
reagents, conditions, mechanism for halogenoalkane to alcohol?
• sodium hydroxide • aqueous solution, warm • nuceleophilic substitution
reagents, conditions, mechanism for dihalogenoalkane to diol?
• aqueous NaOH • heat under reflux • nucelophilic substitution
reagents, conditions, mechanism for halogenoalkane to alkene ?
• sodium hydroxide • ethanol • elimination
reagents, conditions, mechanism for halogenoalkane to nitrile?
• KCN • aqueous ethanolic, heat under reflux • nucleophilic substitution
reagents, conditions, mechanism for halogenoalkane to primary amine?
• alcoholic NH3 • heat under pressure in sealed vessel • nucleophilic substitution
reagents, conditions, mechanism for alkene to halogenoalkane?
• HBr or HCl • room temperature • electrophilic addition
reagents, conditions, mechanism for alkene to dihalogenoalkane?
• Br2 or Cl2 • room temp • electrophilic addition
conditions and mechanism for alkene to (poly)alkene?
• high temperature, high pressure, catalyst • addition polymerisation
conditions and 2 stages for alkene to alcohol (industrial alcohol production)?
• acid catalyst, temp of 300 degrees celsius, pressure of 60 atm • stage 1 - electrophilic addition with H2SO4/H3PO4 • stage 2 - warm with H2O, hydrolysis (H2SO4 catalyst regenerated)
conditions for ethanol production (fermnetation of glucose)?
• anaerobic • temp of 40 degrees • in solution
reagents, conditions, mechanism for primary alcohol to aldehyde?
• acidified potassium dichromate (VI) • excess alcohol, warm gently and distil aldehyde as it forms • partial oxidation
reagents, conditions, mechanism for primary alcohol to carboxylic acid?
• acidified potassium dichromate (VI) solution • excess acidified potassium dichromate (VI) solution, heat under reflux • oxidation
reagents, conditions, mechanism for aldehydes to carboxylic acids?
• acidified potassium dichromate (VI) solution • excess oxidising agent, heat under reflux • oxidation
reagents, conditions, mechanism for secondary alcohol to ketone?
• acidified potassium dichromate (VI) solution • heat under reflux • oxidation
reagents, conditions, mechanism for aldehydes/ketones to primary/secondary alcohol?
• NaBH4 in aqueous ethanol • room temperature and pressure • nucleophilic addition (reduction)
reagents, conditions, mechanism for aldehyde/ketone to hydroxynitrile?
• potassium cyanide and dilute sulfuric acid • room temperature and pressure • nucleophilic addition
reagents, conditions, mechanism for alcohol to ester?
• carboxylic acid and H2SO4 catalyst • heat • esterification
reagents, conditions, mechanism for carboxylic acid to ester?
• alcohol and H2SO4 catalyst • heat • esterification
conditions for forming esters?
carboxylic acid and alcohol in prescence of acid catalyst
reagents for hydrolysing esters?
aqueous NaOH or acids
conditions for forming soap (hydrolyse veg oils/animal fats)?
heat with concentrated NaOH under reflux