A3.2 - Group 7
暂无描述。系统推荐的高质量记忆内容,适合每天坚持背诵学习。
卡片预览 (24 张)
Appearance and state at RTP: Flourine
F2 pale yellow gas
Appearance and state at RTP: chlorine
Cl2 pale green gas
Appearance and state at RTP: bromine
Br2 red-brown liquid
Appearance and state at RTP: iodine
I2 grey solid
Appearance and state at RTP: astatine
At2 black solid
What is the trend in boiling point down group 7?
• more electrons • stronger London forces • more energy required to break the intermolecular forces • boiling point increases
What sub-shells are the electrons in?
2 in s sub-shell 5 in p sub-shell
What is the most common type of reaction of halogens?
redox reactions
What happens to each halogen during redox reactions?
each halogen is reduced gaining 1 electron to form 1- halide ion halogen is called oxidising agent
Where are halogen-halide displacement reactions carried out?
carried out on test tube scale
What does halogen-halide displacement reactions show down group 7?
reactivity decreases down the group
How is halogen-halide displacement reaction carried out?
a solution of each halogen is added to aqueous solutions of the other halides –> a reaction takes place, the halogen displacing the halide from solution –> the solution changes colour
Colour of solution in water: Cl2
pale green
Colour of solution in water: Br2
orange
Colour of solution in water: I2
brown
Halogen-halide displacement reaction: CL- + Br2
no reaction
Halogen-halide displacement reaction: Cl- + I2
no reaction
Halogen-halide displacement reaction: Br- + Cl2
orange colour from Br2 formation
Halogen-halide displacement reaction: Br- + I2
no reaction
Halogen-halide displacement reaction: I1 + Cl2
violet colour from I2 formation
Halogen-halide displacement reaction: I- + Br2
violet colour from I2 formation
Explain the trend in reactivity down group 7.
• atomic radius increases • shielding increases • less nuclear attraction • reactivity decreases
Which halogen is the strongest oxidising agent?
flourine
Define the term disproportionation.
redox reaction in which the same element is both oxidised and reduced