INORGANIC CHEM - REACTIONS OF IONS IN AQ SOLUTION
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What colour is a solution of [Cu(H2O)6]^2+ ions?
blue
What colour is a solution of [Fe(H2O)6]^2+ ions?
green
What colour is a solution of [Fe(H2O)6]^3+ ions?
yellow-brown
What colour is a solution of [Al`(H2O)6]^3+ ions?
colourless
Why can complexes act as acids?
• metal ion weakens O-H bond in water ligand • this can break the bond forming OH^- ligand and H^+ in solution
How does the charge of a complex affect acidity? Why?
• as charge of the complex increases, acidity decreases • metal complexes with a higher charge weaken the OH bond most
[Fe(H2O)6]^2+ with OH^-: - observation - equation
• green solution -> green ppt • [Fe(H2O)6]^2+ + 2OH^- -> [Fe(H2O)4(OH)2] + 2H2O
[Cu(H2O)6]^2+ with OH^-: - observation - equation
• blue solution -> blue ppt • [Cu(H2O)6]^2+ + 2OH^- -> [Cu(H2O)4(OH)2] + 2H2O
[Fe(H2O)6]^3+ with OH^-: - observation - equation
• brown solution -> brown ppt • [Fe(H2O)6]^3+ + 3OH^- -> [Fe(H2O)3(OH)3] + 3H2O
[Al(H2O)6]^3+ with OH^-: - observation - equation
• colourless solution -> white ppt • [Al(H2O)6]^3+ + 3OH^- -> [Al(H2O)3(OH)3] + 3H2O
[Fe(H2O)6]^2+ with excess OH^-: - observation - equation
• no visible reaction • no equation
[Cu(H2O)6]^2+ with excess OH^-: - observation - equation
• no visible reaction • no equation
[Fe(H2O)6]^3+ with excess OH^-: - observation - equation
• no visible reaction • no equation
[Al(H2O)6]^3+ with excess OH^-: - observation - equation
• white ppt -> colourless solution • [Al(H2O)6]^3+ + 4OH^- -> [Al(H2O)2(OH)4]^- + 4H2O • [Al(H2O)3(OH)3] + OH^- -> [Al(H2O)2(OH)4]^- + H2O
[Fe(H2O)6]^2+ with NH3: - observation - equation
• green solution -> green ppt • [Fe(H2O)6]^2+ + 2NH3 -> [Fe(H2O)4(OH)2] + 2NH4^+
[Cu(H2O)6]^2+ with NH3: - observation - equation
• blue solution -> blue ppt • [Cu(H2O)6]^2+ + 2NH3 -> [Cu(H2O)4(OH)2] + 2NH4^+
[Fe(H2O)6]^3+ with NH3: - observation - equation
• brown solution -> brown ppt • [Fe(H2O)6]^3+ + 3NH3 -> [Fe(H2O)3(OH)3] + 3NH4^+
[Al(H2O)6]^3+ with NH3: - observation - equation
• colourless solution -> white ppt • [Al(H2O)6]^3+ + 3NH3 -> [Al(H2O)3(OH)3] + 3NH4^+
[Fe(H2O)6]^2+ with excess NH3: - observation - equation
• no visible reaction • no equation
[Cu(H2O)6]^2+ with excess NH3: - observation - equation
• blue ppt -> deep blue solution • [Cu(H2O)4(OH)2] + 4NH3 -> [Cu(H2O)2(NH3)4]^2+ + 2H2O + 2OH^-
[Fe(H2O)6]^3+ with excess NH3: - observation - equation
• no visible reaction • no equation
[Al(H2O)6]^3+ with excess NH3: - observation - equation
• no visible reaction • no equation
[Fe(H2O)6]^2+ with CO3^2-: - observation - equation
• green solution -> green ppt • [Fe(H2O)6]^2+ + CO3^2- -> FeCO3 + 6H2O
[Cu(H2O)6]^2+ with CO3^2-: - observation - equation
• blue solution -> blue-green ppt • [Cu(H2O)6]^2+ + CO3^2- -> CuCO3 + 6H2O