3.1.9 Rate equations
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What is meant by the order of a reaction?
The power of concentration term in a rate equation
What is zero order? (1)
• As the concentration of reactants changes, the rate remains the same
What is first order? (1)
As the concentration of reactants changes by a factor, the rate changes by the same factor
What is second order? (1)
As the concentration of reactants changes by a factor, the rate increases by that factor squared
Draw a graph of zero order reaction (2)
STraight line but use quizlet or mak e your own flashcrads
Draw a graph of first order reaction (2)
Positive correlation but use quizlet an dkake your flahsctrards
Draw a graph of second order reaction (2)
quizlet
Which reactants will not have appear in rate equation? (1)
Those that don’t have an effect on the rate of reaction (zero order)
Write the general rate equation (3)
rate = k[A]^m[B]^n Rate = rate of reaction in units mol dm⁻³ s⁻¹ k = The rate constant of the reaction (discussed later) m = The order of reaction with respect to [A] n = are orders of reaction with respect to [B]
What is the overall order? (1)
Sum of all orders i.e. m+n
What is the slowest stage in a reaction mechanism called? (1)
The rate determining step
What is the relationship between the reaction mechanism and the rate equation? (1)
The steps up to and including the rate-determining step contain the same species as those shown in the rate equation, in the correct ratio.
What is the rate constant k? (1)
Relates the reactant concentrations to the rate at a particular temperature
What is the relationship between rate and k? (2)
• As rate increases, the value of k also increases • This relationship is described by arrhenius equation
State the arhenius equation
k=Ae^-Ea/RT k= Rate constant A= Arhenius constant same units as k Ea= ACtivation energy Jmol^-1 R= Gas constant= 8.31 JK^-1mol^-1 T=Temp=K
STate the logarithmic arrheniujs equation
In k= In A - Ea/RT
In graphical analysis of arrhenius equation, what is represented by the gradient?
-Ea / R
In graphical analysis of arrhenius equation, what is represented by the y intercept?
LnA
In graphical analysis of arrhenius equation, what is represented by y?
lnK
In graphical analysis of arrhenius equation, what is represented by x?
1/T
How does a concentration-time graph look like for zero order reactions? (3)
Quizlet
How does a concentration-time graph look like for first order reactions? (3)
QUizlet
How does a concentration-time graph look like for second order reactions? (3)
Quizlet
Factors affecting K
as Ea increases k decreases T increases K increases As rate increases K increases