Day 2: Periodic Trends and Bonding
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Metals _____ electrons
lose
Non-Metals_____ electron
gain
Z-S =Zeff
Greater Zeff = smaller the atomic radius. Electrons are held closer to nucleus
Ionic radius increases
Down and to the left France has wine & cheese = Fr biggest atomic radius
Isoelectronic series
Most (+) smallest radius Most (-) largest radius
1st Ionization energy
Energy needed to remove an electron from the first shell endothermic oxidation **Exceptions - B, O, N)
Electron affinity
energy change associated with gaining an electron Trend: to the right ( more (-)) Ionic bonding Exothermic Reduction
Electronegativity
Increases up and to the right Covalent bonding Exceptions: Be/N
More polar bond
Bigger electronegativity difference
Covalent network solids
Diamond & Quartz non-metal with non-metal Sharing e-
Ionic (ionic crystals)
metal with non-metal crystaline, high melting/boiling point brittle
Metalic (metalic lattices)
metal with metal Valance e- loosely held Electrical/thermally conductive Ductile- draw them into wires easily & malleable luster/shiny high melting/ boiling point
Molecular
lower m.p. & b.p. 2 non-metals
Lewis dot structures
***Exceptions: CH4, CO2, SF4)
Polar covalent bonds
electrons shared by the atoms spend a greater amount of time, on the average, closer to the more electronegative atom, causing a dipole
Coordinate covalent bonds
A covalent bond is formed by two atoms sharing a pair of electrons. The atoms are held together because the electron pair is attracted by both of the nuclei. Lewis base & Lewis Acid NH3 + HCl –> NH4Cl
Exceptions to the octet rule
H -2 Be- 4 B- 6 Al- 6 Can exceed octet- 3rd row or lower odd #
Atoms on the left of the fisher projection
Axial position
Atoms on the right of the fisher projection
Equatorial position Lone pairs are put here due to large repulsion
Hybirdization
Electrons are promoted (sp, sp2, sp3, sp3d, sp3d2)
Electron domain - 2 non bonding pairs of e- = 0
sp 180 degrees Electron Geometry -linear Molecular Geometry- linear
Electron domain - 3 non bonding pairs of e- = 0
sp2 120 degrees EG- Trigonal planar MG- Trigonal planar
Electron domain - 3 non bonding pairs of e- = 1
sp2 120 degrees EG- Trigonal planar MG- Bent
Electron domain - 4 non bonding pairs of e- = 0
sp3 109.5 dgrees EG- Tetrahedral MG-tetrahedral