Acrylic Resin
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what are the ideal properties of a denture
replaces function of natural teeth goes into patients mouth is seen by other people has to give value for money
what are the ideal properties of a denture base
dimensionally accurate and stable high softening temperature unaffected by oral fluids thermal expansion low density high thermal conductivity radiopaque non toxic, non-irritant easy and inexpensive to manufacture easy to repair
what are the mechanical properties of a denture base
high youngs modulus high proportional limit high transverse strength high fatigue strength high impact strength high hardness/abrasion resistance
what is free radical addition polymerisation
chemical union of two molecules either the same or different to form a larger molecule without the loss of smaller molecule involves molecules with C=C bonds
what are the stages of acrylic polymerisation
activation - provide free radicals initiation - break C=C bonds propagation - growing polymer chain termination - of polymerisation
what is the initiator of a heat cured acrylic powder
benzoyl peroxide
what are the properties of acrylic
non-toxic non-irritant unaffected by oral fluids poor mechanical properties good fatigue strength high hardness thermal expansion same as artificial tooth low thermal conductivity low density high softening temperature fairly accurate
what is the initiator of a self cured acrylic
benzoyl peroxide but it is activated by tertiary amine in liquid
why use a self cured acrylic
lower temperature so less thermal conduction and better dimensional accuracy
what are the disadvantages of self cured acrylic
low molecular weight so poorer mechanical properties more unreacted monomer = irritant and soften denture base water absorption means expansion
how much unreacted monomer is present in self cure
3-5%
how much unreacted monomer is present in heat cure
0.2-0.5%
what attempts are made to strengthen acrylic resin dentures
high impact resistant materials incorporate fibres
what is ultra hi
high impact heat cure acrylic resin
what properties does ultra hi have
exceptional flexural strength and fracture toughness allowing it to bend a bit which stops it being brittle
when would light activated denture resins be used
customised impression tray material and for repair of fractured dentures
what is the disadvantage of using nylon
water absorption so swelling and softening
what materials can be used as polymers if someone if allergic to acrylic
nylons vinyl polymers polycarbonates
what is the disadvantage of vinyl polymers
softening in use
what is the disadvantage of polycarbonates
distortion in use