Organic 2 Section 3 - Unit 28: Amines
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Give the reagent and conditions used to ensure that a primary amine is formed from the reaction of a halogenoalkane and ammonia (2 marks)
• NH₃ - In excess
Explain why butylamine is a stronger base than ammonia (2 marks)
• Lone pair (on N) - R group increases electron density / donates electrons
State and explain the difference in base strength between phenylamine and ammonia (3 marks)
• Phenylamine weaker • Lone pair on N (less available) • Delocalised into ring
Explain why ethylamine is a Brønsted-Lowry base (2 marks)
• Lone pair on N - Accepts a proton
Why is phenylamine a weaker base than ethylamine (2 marks)
• Lone pair less available - Due to delocalisation
Explain why 2-aminopentane is a stronger base than ammonia (2 marks)
In 2-aminopentane: • Lone pair on N more available or Lone pair on N accepts H+ better • Because of alkyl electron pushing /inductive effect