Module 2: ACIDITY AND BASICITY OF ORGANIC COMPOUNDS
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• acids and bases are defined through three main concepts:
✓ Arrhenius Theory ✓ Brønsted-Lowry Theory ✓ Lewis electron pair Theory
BRønsted-Lowry Theory • a “base” is any species that can _________________ • a Brønsted-Lowry base must have at least one lone pair of electron to be able to form bond with a proton
accept a proton
gives the exact strength of a given acid in water
Ka (acidity constant)
ArrHenius Theory • “acid” is any species that can increase the concentration of ______________ in an aqueous solution
hydrogen ions (protons) HCl → H+ + Cl–
ArrHenius Theory • “base” is any species that can increase the concentration of _____________ in an aqueous solution
hydroxide ions, OH–, NaOH → Na+ + OH–
BRønsted-Lowry Theory • an “acid” is any species that can _________________________ • a Brønsted-Lowry acid must have a hydrogen that can dissociate as H+
donate a proton (H+)
___________ react almost completely with water
stronger acids (eg. inorganic acids)
Lewis “electron” pair Theory • an “acid” is a species that can _______________
accept a pair of non-bonding electrons
in a Brønsted-Lowry acid-base reaction a _______________ is the species formed after an acid donates its proton
conjugate base
HCl (aq) + H2O (l) → H3O+(aq) + Cl–(aq) __________ acts as the Brønsted-Lowry acid; __________ is the conjugate base of HCl
• HCl • Cl
react only slightly with water
weak acids (eg. acetic acid)
HCl (aq) + H2O (l) → H3O+(aq) + Cl–(aq) __________ is the Brønsted-Lowry base; ________ is the conjugate acid of the water
• H2O • H3O+
in a Brønsted-Lowry acid-base reaction ____________ is a species formed after the base accepts a proton
conjugate acid
acid strengths are normally given using
pKa values (pKa = –log Ka)
• note that the negative logarithm in the definition of pKa indicates an _____________ between Ka and pKa
inverse relationship
Lewis electron pair Theory • suggest that acids react with bases, ___________, with no change in the oxidation numbers of any atoms
sharing a pair of electrons
Lewis electron pair Theory • a “base” is a species that can ________________
donate a pair of non-bonding electrons
pOH
power of hydroxide
• the Lewis structure of “water” shows that it has a _________________________, therefore acting as the Lewis base
non-bonding pairs of valence electrons
• the reaction between a Lewis acid and a Lewis base gives rise to an _______________
acid-base complex or complex ion
• the “aluminum ion” (Al3+) suggests that it has free orbitals that can ________________________ donated by the water molecules, thereby acting as the Lewis acid
accept pairs of non-bonding electrons
pH means
power of hydrogen
• the acidity and basicity of a substance can be measured in terms of the molar ___________________________ ions, respectively
concentration of the hydrogen (H+) or hydroxide (OH–)
• pOH is defined as the _________________ ion concentration of a substance
negative logarithm of the OH–