4b
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Crude oil
Mixture of hydrocarbons
Crude oil separation
• It is heated, vaporised in a fractional distillation tower (hotter at the bottom, cooler at the top) • Gases travel until the temperature is lower than the boiling point, then they turn into a liquid (except natural gases, which stay as gases and bitumen that comes off at the bottom and never turns into a gas) The boiling point and viscosity decrease as you go down Flammability increases as you go up
Crude oil fractions
• Natural gases • Petrol / Gasoline • Kerosine • Diesel • Fuel oil • Bitumen
Natural gases
Home heating
Petrol / Gasoline
Car fuel
Kerosene
Plane fuel
Diesel
Bus/Lorrie fuel
Fuel oil
Boat/Power station fuel
Bitumen
Roads
Fuel
A substance that releases energy when burnt
Nitrogen oxide formation
• In car engines • If the temperature is high enough, Nitrogen in the air reacts with oxygen to form nitrogen oxygen
Sulfur dioxide formation
• Fuels can contain impurities such as sulfur • When these impure fuels are burnt, sulfur dioxide is produced
Cracking
Spliting larger alkanes(less value) into smaller alkanes(more value) and alkenes (and/or hydrogen) Requires: Heat(600-700 ºC), Catalyst(silica or alumina) Longer alkane –> Shorter Alkane + Alkene
Why is cracking useful
• Produces smaller, more valuable in demand hydrocarbons. • Less demand for longer alkanes • That are used for fuels or polymers