Unit 5
No description yet. This curated deck is ready for daily study.
Card preview (24)
Reaction rate
the speed of a reaction - which can CHANGE over time k
rates are always…
positive
Average rate equation
Δ[A] / Δt (A = products) - Δ[B] / Δt (B = reactants)
Instanteneous Rate
rate for a specific interval of time
Reaction order
the sensetivity of M of the reactants to the rate
Higher reaction order means…
higher sensitivity to changes of molarity
What is the average rate for 2B = C
• 1/2 Δ[B] / Δt
How are exponents figured out in rate reactions?
Experimental data, NOT stochiometric data
How is the rate described?
it is measured by 1. disappearance of reactants 2. appearance of products
What are the four factors for reaction rates?
• M • Surface Area • Temperature • Catalyst
Rate of zero order reaction
rate = k
Rate of first order reaction
rate = k[A]
Rate of second order reacton
rate = k[A]^2
What does the unit for rate always have to be?
M/t
zero order reaction half life
[A]_0 / 2k
first order reaction half life
0.693 / k
second order reaction half life
1 / k [A]_0
Integrated Rate Law (IRL) does what?
determines M at a given point
IRL of zero order
[A]_t = -kt + [A]_0
IRL of first order
ln [A]_t = -kt + ln [A]_0
IRL of second order
1/ [A]_t = kt + 1/[A]_0
If stochiometric coeficcient is a, than the IRL is.. (first order)
ln [A]_t = - (1/a)kt + ln [A]_0
Radioactive Decay
Process by which an unstable atomic nucleus loses energy by emitting energy - isotopes
What are the three radioactive decay particles/waves
alpha particles beta particles gamma rays