1.7 Quantitative Chemistry
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Relative atomic mass
The mass of the atom compared with that of the carbon 12 isotope, which has a mass of exactly 12 and it is the weighted mean mass of the mass numbers
Relative formula mass/ relative molecular mass/ molar mass
The sun of the relative atomic mass of all the atoms present in the formula of a substance
How to calculate Mr
Add all masses together, multiplying by the power when needed
How to calculate percentage of an element in a compound
RAM of element / Mr of whole compound x 100
Mole
A measurement of chemical amounts. The mass of one mole of a substance in grams is numerically equal to the Mr Eg magnesium: mass (24g) / Mr (24) = 1 mole
How to calculate the mass of one mole of a substance
Mr (masses added together)
Mole equation (including rearranged)
n = m / Mr m = n x Mr
Limiting reactant
The one that runs out first
How to calculate percentage yield
Actual yield / theoretical yield x 100
How to calculate reacting masses
Divide known mass by the Mr of its compound/element to get its moles, apply ratio, multiply by the unknown compound/element’s Mr
Why is the percentage yield less than 100%?
Incomplete reaction Impossible to separate product fully out of the reaction mixture Reaction is reversible and may not go to completion As a result of a side reaction
Empirical formula
The simplest whole number ratio of the atoms of each element in a compound
Molecular formula
Actual number of atoms of each element in a molecule
Hydrated
Solid crystals contain water of crystallisation
Anhydrous
Does not contain water of crystallisation
Water of crystallisation
Water that is chemically bonded into the crystal structure of a compound
How can water of crystallisation be removed?
Heating to constant mass
What is heating to constant mass?
Reheating and reweighing until a constant mass is observed. This ensures that all the water of crystallisation has been removed from the hydrated crystals
How to calculate the percentage of water of crystallisation in a compound
Total Mr of water / total Mr of compound x 100
How to calculate the relative formula mass of compounds containing water of crystallisation
Eg finding the x. Make a table for the compound and its woc. Figure out mass, Mr, therefore moles (divide) and the ratio will equal x (when simplified to 1:__)
How to carry out thermal decomposition
Heating to constant mass