C4/5 Acids, Bases and Titrations + NPK :(
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What ions do acids produce
-Hydrogen+ ions -In aqueous solution
What does an alkali aqueous solution contain
• OH - • Hydroxide
What is the pH scale
• Scale from 0 to 14 • Measures how acidic something is • 7 is neutral
Neutralisation reaction
• OH- + H+ –> H20 • water
How to check pH
• Universal Indicator • colour change from red to purple • subjective colour change • phenolphthalein- colourless (acid) or pink (Alkali) • distinct colour change
What are titrations used for
• Procedure where a solution of a known concetration • is used to determine one of an uknown
Titrations method
• Fill the burette with acid –> measure volume accurately (drippy tall one) • Add 25cm3 of alkali to concical flask using pipette –> fixed volume (uses the epi pen/ ballon) • place on white tile • Add 2-3 drops of phenolphthalein into the aklali in the conical flask • Take reading from the burrette of acid, add acid, swirling conituously until a colour change • colourless –> pink • repeat again (this time you know when to slow down) • add drop by drop at the end • Record how much aicd was used (initially reading of acid - what is left in the burrette) • Repeat until concordant results are achieved
What are concordant results
• results that are within • 0.1cm3 of each other
Titration calculations
• READ REALLY CAREFULLY • Use a table • Fill in mol, vol, conc • use equation mol = vol x conc
What is a strong acid
• Completely ionise in solution • Hydrochloric acid • Sulfuric acid • Nitric acid
pH increase/decrease
• If pH decreases by 1 • Concentration increases by factor 10
Weak acid
• Partially ionises in solution • Reversible • Ethanoic acid • Citric acid
Dilute and concentrated meaning
• High/ low concentration of H+ ions • higher conc = lower pH
what is an NPK fertaliser
• Nitrogen • Phosphorus • Potassium • a formulation
NPK: What is ammonia used for
• Nuetralisation reactions • acid + ammonia –> salt • ammonia + nictric acid –> ammonium nitrate
How can we get fertalisers
• Potassium chloride = mined • Potassium sulphate = mined • Phosphate rock = mined BUT is insoluble
How to treat phosphate
• React with acid
Mined phosphate + nitric acid
• calcium nitrate
Mined phosphate + sulfuric acid
• Single super phosphate
Mined phosphate + phosphoric acid
• triple super phosphate