Transition elements
No description yet. This curated deck is ready for daily study.
Card preview (24)
d-block element
An element with its highest energy e- in the d-subshell
transition metal
A d-block element which forms at least one ion with an incomplete d-subshell
What three types of reactions can transition elements undergo?
• ligand exchange • precipitate • redox
chemical properties of transition elements (4)
• colourful • good catalysts • variable oxidation states • complex ions with variety of ligands
physical properties of transition elements (5)
• ductile • malleable • high melting/boiling pt • hard/dense • sonorous
Why are transition elements good catalysts?
• variable oxidation states • provide a surface which can absorb reactants (form complex ions)
two examples of reactions which use transition metals as catalysts
• Ni (alkene –> alkane) • V2O5 Contact process (SO2 + O2 –> 2SO3)
ligand
A molecule or ion that can donate a pair of e- to the transition metal ion
complex ion
A transition metal bonded to ligands by coordinate bonds
coordinate number
Total number of coordinate bonds between a central metal ion and ligands
shape of complex ion with 4 coordinate bonds
• square planar (90°) • tetrahedral (109.5°)
shape of complex ion with 6 coordinate bonds
octahedral (90°)
bidentate ligands
ligands with two lone pairs of e-: - en - ethanedioate (2-)
hexadentate ligands
ligands with six lone pairs of e-: - edta (4-)
neutral ligands (monodentate)
• H2O • NH3
charged ligands
• Cl- • OH- • CN- • SCN-
which two transition metals have unusual e- configurations?
Cr and Cu
which d-block elements are not transition elements?
• Zn (Zn2+ has a full d-subshell) • SC (Sc3+ doesn’t have a d-subshell)
Cu2+ with NaOH(aq)
blue solution –> blue ppt Cu(OH)2(s) ppt insoluble in excess
Fe2+ with NaOH(aq)
pale green solution –> dark green ppt (goes brown on standing in air) Fe(OH)2(s) ppt insoluble in excess
Fe3+ with NaOH(aq)
pale yellow solution –> orange brown ppt Fe(OH)3(aq) ppt insoluble in excess
Mn2+ with NaOH(aq)
pale pink solution –> light brown ppt (darkens on standing in air) Mn(OH)2(s) ppt insoluble in excess
Cr3+ with NaOH(aq)
violet solution –> grey green ppt Cr(OH)3(s) ppt dissolves in excess to form a dark green solution [Cr(OH)6]3-(aq)
which ions react the same way with NH3(aq) as they do with NaOH(aq)
Fe2+ Fe3+ Mn2+