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Chapter 31 - Organic Synthesis and Analysis

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Total cards: 24•Content version: v4•Public deck•Updated: 8/1/2026

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#1
Front (Question)

conditions, reagents, mechanism: alkene to haloalkene

Back (Answer)

aqueous HBr, electrophilic addition

#2
Front (Question)

conditions, reagents, mechanism: haloalkane to alkene

Back (Answer)

ethanolic, hot NaOH, basic elimination

#3
Front (Question)

conditions, reagents, mechanism: alkene to dihaloalkane

Back (Answer)

aqueous Br2, rtp, UV, electrophilic addition

#4
Front (Question)

conditions, reagents, mechanism: alkene to diol

Back (Answer)

KMnO4, OH-, electrophilic addition

#5
Front (Question)

conditions, reagents, mechanism: alkene to alkane

Back (Answer)

H2 and Ni catalyst, hydrogenation

#6
Front (Question)

conditions, reagents, mechanism: alkene to alkyl hydrogensulfate

Back (Answer)

H2SO4, rtp, electrophilic addition

#7
Front (Question)

conditions, reagents, mechanism: alkene to prim alcohol

Back (Answer)

steam, 300 degrees celsius, concentrates strong acid catalyst, oxidation

#8
Front (Question)

conditions, reagents, mechanism: primary/secondary alcohol to alkene

Back (Answer)

hot excess H2SO4, Al2O3/zeolite catalyst, 600K

#9
Front (Question)

conditions, reagents, mechanism: haloalkane to secondary alcohol

Back (Answer)

NaOH aqueous, warm, nucleophilic substitution

#10
Front (Question)

conditions, reagents, mechanism: secondary alcohol to haloalkane

Back (Answer)

HBr, conc H2SO4, nucelophilic substitution

#11
Front (Question)

conditions, reagents, mechanism: primary haloalkane to nitrile

Back (Answer)

KCN, ethanolic and heat, nucleophilic substitution

#12
Front (Question)

conditions, reagents, mechanism: nitrile to carboxylic acid

Back (Answer)

Hydrogen ions under reflux in oxidation

#13
Front (Question)

conditions, reagents, mechanism: nitrile to amine

Back (Answer)

H2 and Ni catalyst

#14
Front (Question)

conditions, reagents, mechanism: haloalkane to quaternery ammonium salt

Back (Answer)

excess ammonia, high pressure, nucelophilic addition

#15
Front (Question)

conditions, reagents, mechanism: alcohol to ketone

Back (Answer)

secondary alcohol, acidified potassium dichromate, heat under reflux, oxidation

#16
Front (Question)

conditions, reagents, mechanism: alcohol to aldehyde

Back (Answer)

primary alcohol, acidified potassium dichromate, heat under distillation, oxidation

#17
Front (Question)

conditions, reagents, mechanism: alcohol to carboxylic acid

Back (Answer)

primary alcohol, acidified potassium dichromate, heat under reflux, oxidation

#18
Front (Question)

conditions, reagents, mechanism: aldehyde/ketone to hydroxynitrile

Back (Answer)

ethanolic KCN, limited H2SO4, rtp, nucleophilic addition

#19
Front (Question)

conditions, reagents, mechanism: alkyl hydrogensulfate to secondary alcohol

Back (Answer)

water nucleophilic substitution

#20
Front (Question)

conditions, reagents, mechanism: ketone/aldehyde to alcohol

Back (Answer)

NaBH4 and H plus ions, reduction

#21
Front (Question)

conditions, reagents, mechanism: forming ester

Back (Answer)

• alcohol and carboxylic acid - esterification • alcohol and acyl chloride - nucleo add elim • alcohol and acid anhydride - nucleo add elim

#22
Front (Question)

conditions, reagents, mechanism: acyl chloride to N-substituted amide

Back (Answer)

cold prim amine, nucleophilic addition elimination

#23
Front (Question)

conditions, reagents, mechanism: acyl chloride to carb acid

Back (Answer)

water excess, nucleo add elim

#24
Front (Question)

conditions, reagents, mechanism: carb acid to acyl chloride

Back (Answer)

SOCl2 rtp