3.1.4 qualitative analysis
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Test for carbonate
Add dilute acid and observe effervescence Bubble gas through limewater. CO2 - will turn limewater cloudy 2HCl + Na2CO3 > 2NaCl + H2O + CO2
Test for sulfate
Acidified BaCl2 used as reagent Will form white precipitate Ba2+ + SO4^2- > BaSO4 (s)
Testing for halide ions
Test solution is made acidic with nitric acid Add Silver nitrate - AgNO3 Chlorine - white Bromine - cream Iodine - pale yellow Nitric acid reacts with any carbonates to prevent formation of precipitate Ag2CO3
If halide colour too similar
AgCl dissolves in dilute ammonia AgBr dissolves in concentrated ammonia AgI doesnt react - too insoluble
Sequence of tests
Carbonate, sulfate then halide Prevents false results as both BaCO3 and Ag2SO4 are insoluble
Testing for positive ions (cations)
Test for NH4+ Reaction with warm NaOH, forming NH3 gas Turns red litmus paper blue