Bonds
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What is a covalent bond
Electrostatic attraction between the shared pair of electrons and the positive nuclei
Ionic bond
An electrostatic attraction between positive ions and negative ions
Metallic bond
An electrostatic attraction between positive ions and delocalised electrons
What happens in coordinate bonding
Both electrons are donated from 1 atom to the empty orbital of another
What is the shape of a simple molecule determined by
The electrons and bonds in it. This is because electron pairs repel each other and therefore try to get as far away as possible
Shapes of simple covalent molecules 2 pairs of electrons
Linear molecule 180 degrees
Shapes of simple covalent molecules 3 pairs of electrons
Trigonal planar 120 degrees
Shapes of simple covalent molecules 4 pairs of electrons
Tetrahedral 109.5 degrees
Shapes of simple covalent molecules 5 pairs of electrons
Trigonal bipyramidal 120 degrees & 90 degrees
Shapes of simple covalent molecules 6 pairs of electrons
Octahedral (8 faces) 90 degrees
What affects the shape of an atom
As well as bonding pairs of electrons repelling, any lone pairs that are around the central atom also affects the shape
What repels more lone pairs or bonding pairs
Lone pairs repel more
4 pairs of electron 3 bonding 1 lone pair
Pyramidal 107.5 degrees
4 pairs of electrons 2 bonding pairs, 2 lone pairs ( e.g. H20)
V - shaped / bent 104.5 degrees
5 pairs of electrons 4 bonding, 1 lone pair
Modified Trigonal bipyramid
5 pairs 3 bonding, 2 lone pairs
T shaped
6 pairs 4 bonding, 2 lone pairs
Square planar
How to determine the shape
1) group number of central atom 2) number of bonding atoms 3) charge 4) add up and divide by 2 5) work out lone pairs , total - bonding
What is electronegativity
The ability of an atom to attract the pair of electrons(/electron density) in a covalent bond towards itself
What would happen with Cl2 due to electronegativity
Nothing would happen because there is no difference in electronegativity, so we have a non-polar covalent bond
Ht would happen in HCL due to electronegativity
Chlorine is more electronegative that hydrogen , this is a polar bond
What does electronegativity depend on
• nucleus charge • atomic radius • electron shielding
What is the most electronegative element
F Fluorine
How to increase electronegativity
More protons and a smaller radius increases attraction from the nucleus