Part-2 organic chem
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carbon sp3
tetrahedral 109.5 4 singles
carbon sp2
trigonal planar 120 1 double and 2 single
carbon sp
linear 180 1 triple and 1 single bond or 2 double bond
oxygen sp3
tetrahedral - electron bent - molecular
oxygen sp2
trigonal planar - electron linear- molecular
nitrogen sp3
tetrahedral- electron pyrimidal- molecular
nitrogen sp2
trigonal planar- electron bent- molecular
nitrogen sp
linear- electron linear - molecular
more symmetrical, less polar will? bp
lowering boiling point
melting point
may or may not follow this general rule, as a more symmetrical molecule typically packs better, requiring more energy (higher melting point) to melt the solid
bond length
length character the shorter the bond,
alkane formula
C(n)H(2n+2)
bp in hydrocarbons vs. electronegative
hydrocarbons, bp increase with more number of carbon (molecular weight or molar mass) electronegative atoms, increase bp when compared to a molecule of similar weight with a less polar group or if hydrogen bonding is possible
organic compounds tend to be
combustible
base acid nucleophile electrophile
base- proton acceptor acid- proton donor nucleophile- electron donor with the formation of a bond lewis base electrophile- electron acceptor lewis acid
strong acids because
cb is 1) charge 2) size, electronegativity 3) resonance 4) inductive
iso propopylnol isopropylcyclopentane
three carbons coming off of the carbons
isobutane
ch3 off of the second carbon Ch3(ch3) coming off of chch3 total carbon 4 even with the coming off one
isopentane
ch3 (ch3)coming off of the chch2ch3 total carbon 5 even with the coming off one
neopentane
ch3( ch3)2 coming off from both sides of cch3 total carbon 5 even with the coming off ones
alkane alkene alkyne
alkane= c-c alkeyne= c=c alkyne= c (triple bond) c
nitrile
R-c (triple bond) n
alcohol
R-OH
amines 1st degree 2nd degree 3rd degree
R-NH2 R-NH-R R-N-R n with three r coming off of it l R