electrode potential 3.1.11 in papers 1+3
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what is a salt bridge?
• allows for free moving ions • pottasium nitrate • should be unreactive with electrodes and their solutions
why use a high resistance voltmeter?
• to stop the electrons from flowing in a circuit • in this state its posible to meaure the maximum potential difference
what happens if the voltmeter is replaced with a bulb?
• a current flows • reaction will happen at each electrode • voltage falls to 0 as reactants are used up
what type of agent is at the positive electrode?
oxidising
what type of agent is at the negative electrode?
reducing
when is Pt included in cell diagrams?
when there isnt a solid
what are the standard conditions of a standard hydrogen electrode?
• 100kpa • 298k • 1moldm3 • pt electrode
what is the E0 value of a SHE?
0
how to calculate Ecell?
Erhs-Elhs
what does it mean if E0 value is more negative?
• equilibrium lies to the left • more easy it is to loose an electron anf form ions • making it a strong reducing agent
what happens if you increase the pressure?
• equilibrium shifts to the left • making the E naught value more negative
what happens when you increase Pt surface area?
• no effect • doesnt affect the ions
what happens when the concetration of H+ increases?
• shifts equilibrium to the right • Ecell value becomes more positive
what happens when the tempreture increases?
• equilibrium will shift to the left • Ecell value becomes more negative
can a reaction happen if an Ecell value is negative?
• no • the more positive it is, the more likely for the reaction is to happen
why does a fuel cell not need to be electrically recharged?
supplied continously
whats the half equation for the negative electrode of a alkaline hyodrogen-oxygen cell?
h2 + 2OH- -> 2h2o + 2e-
whats the half equation for the positive electrode of a alkaline hyodrogen-oxygen cell?
o2 + 2h2o + 4e- -> 4OH-
why is it not neccesary to replace KOH eletrolyte in a hydrogen-oxyfen fuel cell?
OH- ions produced in 1 equation are used in another
describe how reactions at the electrodes generate an electric current that can power the motor in the external circuit.
• electrons are released • electrons pass through the motor