Chemical Tests
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Test for Sulphate Ions
• Acidify with dilute HCl • Add Barium Chloride • White precipitate of Barium Sulphate
Test for carbonate ions
• Add dilute HCl • Effervesence, gas produced turns limewater cloudy
Test for OH- ions
Damp red litmus paper turns from red to blue
Test for Mg 2+
• In seperate test tubes add dilute NaOH and dilute H2SO4 to seperate sample of Mg2+ • With OH-, white precipitate forms. • No change with sulphate ions
Flame test for Ca2+
Brick-red
Test-tube test for Ca2+
• In seperate test tubes add dilute NaOH and dilute H2SO4 to seperate samples of Ca2+ • With OH- there is white precipitate • With sulphate ions a silight white precipitate
Flame test for Sr2+
red
Test tube test for Sr2+
• In seperate test tubes add dilute NaOH and dilute H2SO4 to seperate samples of Sr2+ • With OH- there is no visible change • With sulphate ions a white precipitate forms
Flame test for Ba2+
Green
Test tube test for Ba2+
• In seperate test tubes add dilute NaOH and dilute H2SO4 to seperate samples of Ba2+ • With OH- there is no visible change • With sulphate ions a white precipitate forms
Test for Ammonium ions and give equation
• Add NaOH and heat sample • Hold damp red litmus paper at test tube mouth • Litmus paper will turn from red to blue NH4(+) + OH (-) -> H2O + NH3 Alkalai ammonia turns the litmus for red to blue
Test for Alkene
• Shake with bromine water • Bromine water turns from orange to colourless
Test for halogenoalkane
• Add NaOH and warm • Acidify with nitric acid • Add Silver Nitrate • Observe halide precipitate observations
Test for alcohol
• Add acidified potassium dichromate • Primary and secondary alcohols turns solution from orange to green • Tertiary alcohol remains orange
What would produce a positive test for a tertiary alcohol
• Add metallic Na • Hydrogen effervesence • Squeaky pop if collected and tested with lighted splint
Test for carboxylic acid
• Add sodium carbonate • Effervesence will occur • If collected and bubbled through limewater, limewater will turn cloudy
Name and describe two tests for aldehydes
• Warm with fehlings solution - blue solution forms red precipitate • Warm with tollens reagent - silver mirror forms
Tests part 1 and 2 for halide ions
• Acidify with dilute nitric acid and add silver nitrate • Precipitates: White - Cl-, Cream - Br-, Yellow - I-. • Add dilute ammonia - Cl- redissolves • Add conc ammonia - Br- redissolves • I- does not redissolve